| Identification | More | [Name]
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine | [CAS]
93102-05-7 | [Synonyms]
N-BENZYL-N-(METHOXYMETHYL)-N-TRIMETHYLSILYLMETHYLAMINE
N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine
N-(METHOXYMETHYL)-N-(TRIMETHYLSILYLMETHYL)BENZYLAMINE
N-(METHOXYMETHYL)-N-((TRIMETHYLSILYL) METHYL)(PHENYL)METHANAMINE
N-(Methoxymethyl)-N-(trimethylsilyl) benzylamine
Benzyl-methoxymethyl-trimethylsilanylmethylamine
N-(Methoxymethyl)-N-(trimethyl
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine, HPLC 96%
N-(methoxymethyl)(phenyl)-N-((trimethylsilyl)methyl)methanamine
N-(Methoxymethyl)-N-(phenylmethyl)-1-trimethylsilylmethanamine
N-(Methoxymethyl)-N-[(trimethylsilyl)methyl]benzenemethanamine
[[Benzyl(methoxymethyl)amino]methyl]trimethylsilane
N-(Trimethylsilylmethyl)-N-(methoxymethyl)benzylamine
N-[(Trimethylsilyl)methyl]-N-(methoxymethyl)benzenemethanamine
N-Benzyl-N-methoxymethyltrimethylsilylmethanamine
N-Benzyl-N-(methoxymethyl)-N-trimethylsilymethyamine | [EINECS(EC#)]
630-326-4 | [Molecular Formula]
C13H23NOSi | [MDL Number]
MFCD00674005 | [Molecular Weight]
237.41 | [MOL File]
93102-05-7.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow liquid | [Boiling point ]
76 °C0.3 mm Hg(lit.)
| [density ]
0.928 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.492(lit.)
| [Fp ]
151 °F
| [storage temp. ]
Refrigerator | [solubility ]
Soluble in chloroform, ethyl acetate. | [form ]
Liquid | [pka]
7.29±0.50(Predicted) | [color ]
Clear colorless to light yellow | [Specific Gravity]
0.928 | [Hydrolytic Sensitivity]
2: reacts with aqueous acid | [Sensitive ]
Moisture & Light Sensitive | [BRN ]
4311216 | [InChIKey]
RPZAAFUKDPKTKP-UHFFFAOYSA-N | [CAS DataBase Reference]
93102-05-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
1993 | [WGK Germany ]
3
| [HazardClass ]
3 | [PackingGroup ]
Ⅲ | [HS Code ]
29319090 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Sodium hydroxide-->Ethyl acetate-->Formaldehyde-->Benzylamine-->Chloromethyltrimethylsilane | [Preparation Products]
CIS-5-BENZYLTETRAHYDROPYRROLO[3,4-C]PYRROLE-1,3(2H,3AH)-DIONE-->1-Benzyl-3-trifluoromethyl-pyrrolidine-3-carboxylic acid-->Ethyl 1-benzyl-4,4-diMethylpyrrolidine-3-carboxylate-->3,4-Pyrrolidinedicarboxylic acid, 1-(phenylmethyl)-, 3,4-dimethyl ester, (3S,4S)--->2-BENZYL-HEXAHYDRO-CYCLOPENTA[C]PYRROL-4-ONE-->Methyl DL-1-benzyl-4-phenylpyrrolidine-3-carboxylate |
| Hazard Information | Back Directory | [Chemical Properties]
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine is clear colorless to light yellow liquid
| [Physical properties]
bp 77–80°C/0.5 mmHg. |
| Questions And Answer | Back Directory | [Preparation]
N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine is most conveniently prepared by treatment of benzylamine with chloromethyltrimethylsilane followed by formaldehyde and methanol. Access to higher ether homologs is achieved by replacing methanol with the appropriate alcohol. An alternate procedure involves alkylation of lithium N-benzyltrimethylsilymethylamide with methoxymethyl chloride.
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