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ChemicalBook--->CAS DataBase List--->82-49-5

82-49-5

82-49-5 Structure

82-49-5 Structure
IdentificationMore
[Name]

1-Anthraquinonesulfonic acid
[CAS]

82-49-5
[Synonyms]

1-ANTHRAQUINONE SULFONATE
1-ANTHRAQUINONESULFONIC ACID
1 SULFOANTHRAQUINONE
9,10-anthraquinone-1-sulfonic acid
a-Anthraquinonesulfonic acid
ALPHA-SULFOANTHRAQUINONE
9,10-dihydro-9,10-dioxo-1-anthracenesulfonicaci
9,10-Dihydro-9,10-dioxo-1-anthracenesulfonicacid
9,10-dioxoanthracene-1-sulphonicacid
Anthraquinone-1-sulfonicacid
-Sulphoanthraquinone
9,10-dioxo-9,10-dihydroanthracene-1-sulfonic acid
anthraquinone 1-sulfonate
1-ANTHRAQUINONESULPHONICACID
9,10-Dioxo-1-anthracenesulfonic acid
9,10-Dioxo-9,10-dihydro-1-anthracenesulfonic acid
[EINECS(EC#)]

201-427-7
[Molecular Formula]

C14H8O5S
[MDL Number]

MFCD00019152
[Molecular Weight]

288.28
[MOL File]

82-49-5.mol
Chemical PropertiesBack Directory
[pka]

pK1: 0.27 (25°C)
[CAS DataBase Reference]

82-49-5(CAS DataBase Reference)
[EPA Substance Registry System]

82-49-5(EPA Substance)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

FUMING SULFURIC ACID-->Anthraquinone-->Mercury-->1-Anthracenesulfenic acid, 9,10-dihydro-9,10-dioxo-, methyl ester-->1-Anthracenesulfenic acid, 9,10-dihydro-9,10-dioxo--->1 5-ANTHRAQUINONEDISULFONIC ACID-->1-NITROANTHRAQUINONE-->Sulfuric acid-->Sodium sulfite-->Aluminum chloride-->Benzene-->Nitric acid
[Preparation Products]

1-Aminoanthraquinone-->Disperse Red 9-->Disperse Red 9
Hazard InformationBack Directory
[Uses]

1-Anthraquinonesulfonic Acid Potassium Salt is a related compound of Anthraquinone(A679245). Anthraquinone is an important precursor for many drugs.
[Synthesis]

Anthraquinone-1-sulfonic acid, K salt, also called diamant salt, is prepared by sulfonation in the presence of, e.g., 0.5 % mercury in 20 % oleum, an amount of SO3 adequate for the sulfonation of about 60 % of the charge. The reaction is controlled in such a manner that about 50 % of the anthraquinone remains unsulfonated. After mercury is precipitated as the sulfide, the unreacted anthraquinone is precipitated by dilution and is collected by filtration. After washing and drying, it is recirculated as ‘reclaimed quinone‘. Mercury is removed completely from the filtrate, and the anthraquinone-1-sulfonic acid is then precipitated as the potassium salt .
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

82-49-5(sigmaaldrich)
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