| Chemical Properties | Back Directory |
[Appearance]
clear colorless to light yellow liquid |
[Melting point ]
95-96 °C |
[Boiling point ]
60 °C2 mm Hg(lit.) |
[density ]
1.194 g/mL at 25 °C(lit.)
|
[vapor density ]
5.94 (vs air)
|
[vapor pressure ]
0.1 mm Hg ( 25 °C)
|
[refractive index ]
n20/D 1.416(lit.)
|
[Fp ]
142 °F
|
[storage temp. ]
2-8°C |
[solubility ]
Chloroform (Sparingly) |
[form ]
Liquid |
[color ]
Clear colorless to light yellow |
[Water Solubility ]
Soluble in alcohol and chloroform. Slightly soluble in water. |
[Sensitive ]
Moisture Sensitive |
[BRN ]
471433 |
[Stability:]
Hygroscopic, Moisture Sensitive |
[InChIKey]
LGTLXDJOAJDFLR-UHFFFAOYSA-N |
[LogP]
0.61 |
[CAS DataBase Reference]
814-49-3(CAS DataBase Reference) |
[NIST Chemistry Reference]
Phosphorochloridic acid, diethyl ester(814-49-3) |
[EPA Substance Registry System]
814-49-3(EPA Substance) |
| Safety Data | Back Directory |
[Hazard Codes ]
T+ |
[Risk Statements ]
R23:Toxic by inhalation.
R27/28:Very Toxic in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed .
R34:Causes burns. |
[Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
S7/9:Keep container tightly closed and in a well-ventilated place . |
[RIDADR ]
UN 2927 6.1/PG 1
|
[WGK Germany ]
3
|
[RTECS ]
TD1400000
|
[F ]
10-19-21 |
[TSCA ]
Yes |
[HazardClass ]
6.1(a) |
[PackingGroup ]
II |
[HS Code ]
29199000 |
[Safety Profile]
Deadly poison by skin
contact. Poison by ingestion. A
cholinesterase inhibitor. See also
PARATHION. Trace HCl catalyzes a
hazardous reaction during the preparation of
diethyl phosphate from diethyl
chlorophosphate. When heated to
decomposition it emits very toxic fumes of
Cl and POx. |
[Hazardous Substances Data]
814-49-3(Hazardous Substances Data) |
| Hazard Information | Back Directory |
[General Description]
Clear liquid. This material is used as an intermediate in organic synthesis. |
[Reactivity Profile]
Organophosphates, such as DIETHYL CHLOROPHOSPHATE, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. |
[Health Hazard]
This material is a cholinesterase inhibitor. It has high oral and very high dermal toxicity. It is a skin irritant. It is also toxic by inhalation. |
[Fire Hazard]
Emits very toxic fumes of chloride and phosphorus oxides when heated to decomposition. |
[Description]
Diethyl chlorophosphate is a combustible,clear liquid with an unpleasant odor. Molecularweight=172.76; Boiling point=60℃ at 2.0 mmHg; 81℃at 6.0 mmHg. Freezing/Melting point=0℃. HazardIdentification (based on NFPA-704 M Rating System):Health 4, Flammability 2, Reactivity 2 . Reacts withwater. |
[Chemical Properties]
clear colorless to light yellow liquid |
[Uses]
A phosphorous halide used for biochemical research. Also used as an intermediate in organic synthesis. |
[Potential Exposure]
This material may be used as an intermediate in the manufacture of pesticides and chemical warfare agents. |
[First aid]
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Speed in removing material from skinis of extreme importance. Shampoo hair promptly if contaminated. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includingresuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give conscious victims water or milk.Promote excretion by administering saline cathartic or sorbitol. Do not make an unconscious person vomit. |
[storage]
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from oxidizers and reducing agents.Where possible, automatically pump liquid from drums orother storage containers to process containers. |
[Shipping]
Organophosphorus compound, toxic n.o.s.requires a label of “POISONOUS/TOXIC MATERIALS.”These materials fall in Hazard Class 6.1 and Packing GroupII. |
[Incompatibilities]
Contact with oxidizers may cause therelease of phosphorous oxides. Contact with strong reducingagents, such as hydrides, may cause the formation of flammable and toxic phosphine gas. Strong oxidizers, bases. |