| Identification | Back Directory | [Name]
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE& | [CAS]
811862-77-8 | [Synonyms]
palladium(0)
Bis(3,5,3',5′-diMethoxydibenz
Bis(3,5,3',5'-dimethoxydibenzyL
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
Bis[(1E,4E)-1,5-bis(3,5-diMethoxyphenyl)…
diMethoxydibenzylideneacetone)palladiuM(0)
Bis(3,5,3',5'-dimethoxydibenzylideneacetone)
Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium
Bis(3,3′,5,5′-dimethoxydibenzylideneacetone)palladium
PalladiuM,bis[(1E,4E)-(1,2,4,5-h)-1,5-bis(3,5-diMethoxyphenyl)
Bis(3,5,3',5'-diMethoxydibenzylideneacetone)palladiuM(0), Pd 13%
Bis(3,5,3’,5’-dimethoxydibenzylideneacetone)palladium(0) (Pd(dmdba)2)
PalladiuM,bis[(1E,4E)-(1,2,4,5-h)-1,5-bis(3,5-diMethoxyphenyl)-1,4-pentadien-3-one]- | [Molecular Formula]
2C21H22O5.Pd | [MDL Number]
MFCD07369799 | [MOL File]
811862-77-8.mol | [Molecular Weight]
815.22 |
| Chemical Properties | Back Directory | [Melting point ]
170-178 °C(lit.)
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
Red-brown | [Water Solubility ]
Insoluble in water. | [InChI]
InChI=1S/2C21H22O5.Pd/c2*1-23-18-9-15(10-19(13-18)24-2)5-7-17(22)8-6-16-11-20(25-3)14-21(12-16)26-4;/h2*5-14H,1-4H3;/b2*7-5+,8-6+; | [InChIKey]
RTGAJOPJZJDWAX-XVGSOSPHSA-N | [SMILES]
[CH](C1=CC(OC)=CC(OC)=C1)[CH]C(=O)[CH][CH]C1=CC(OC)=CC(OC)=C1.[CH](C1=CC(OC)=CC(OC)=C1)[CH]C(=O)[CH][CH]C1=CC(OC)=CC(OC)=C1.[Pd] |^1:0,11,14,15,26,37,40,41| |
| Hazard Information | Back Directory | [Uses]
suzuki reaction | [General Description]
Bis(3,5,3′,5′-dimethoxydibenzylideneacetone)palladium(0) is a non-phosphine based Pd(0) catalyst that can catalyze the Suzuki–Miyaura reaction of aryl chlorides with arylboronic acids with higher percentage conversion when compared to tris(dibenzylideneacetone)dipalladium(0) [Pd2(dba)3]. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
|
|