| Identification | Back Directory | [Name]
XPhos Pd G3 | [CAS]
1445085-55-1 | [Synonyms]
XPhos Pd G3
XPhos Pd G3 95%
XPhos-G3-Palladacycle
Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
(2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%
(SP-4-3)-[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium
(SP-4-3)-[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato-κO)palladium
Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [XPhos Palladacycle] | [Molecular Formula]
C46H62NO3PPdS | [MDL Number]
MFCD22666043 | [MOL File]
1445085-55-1.mol | [Molecular Weight]
846.46 |
| Chemical Properties | Back Directory | [Melting point ]
146-151°C (decomposition) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [color ]
white to off-white | [InChIKey]
VXKANHUGMZCOIM-UHFFFAOYSA-N | [SMILES]
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C |
| Hazard Information | Back Directory | [Uses]
XPhos Pd G3 may be used in the following reactions:
- Cyanation reaction of heterocyclic halides.
- Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
- Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.
| [General Description]
XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. |
|
|