| Identification | More | [Name]
Aluminium nitrate nonahydrate | [CAS]
7784-27-2 | [Synonyms]
ALUMINIUM NITRATE 9H2O
ALUMINIUM NITRATE-9-HYDRATE
ALUMINIUM NITRATE ENNEAHYDRATE
ALUMINIUM NITRATE NONAHYDRATE
ALUMINIUM STANDARD
ALUMINUM NITRATE
ALUMINUM NITRATE 9H2O
ALUMINUM NITRATE, 9-HYDRATE
ALUMINUM NITRATE HYDRATED
ALUMINUM NITRATE, HYDROUS
ALUMINUM NITRATE NONAHYDRATE
NITRIC ACID ALUMINUM SALT
aluminum(111)nitrate(1:3)nonahydrate
Aluminum(III)nitrate,nonahydrate(1:3:9)
aluminumnitrate(non-specificname)
Aluminumtrinitratenonahydrate
nitricacid,aluminum(3+)saltnonahydrate
nitricacid,aluminumsalt,nonahydrate
Nitricacid,aluminumsalt,nonahydrate(8CI,9CI)
nitricacid,aluminumsaltnonahydrate | [EINECS(EC#)]
236-751-8 | [Molecular Formula]
AlH18N3O18 | [MDL Number]
MFCD00149132 | [Molecular Weight]
375.13 | [MOL File]
7784-27-2.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystalline powder | [Melting point ]
73 °C(lit.) | [Boiling point ]
100°C/760mmHg | [density ]
1.25 | [storage temp. ]
Store at +5°C to +30°C. | [solubility ]
ethanol: very soluble(lit.) | [form ]
Solid | [color ]
White | [PH]
2.0-4.0 (50g/l, H2O, 20℃) | [Stability:]
Strong oxidizer-contact with combustible material may lead to fire. Incompatible with water, most common metals, organics. Moisture-sensitive. | [Water Solubility ]
64 g/100 mL (25 ºC) | [Sensitive ]
Hygroscopic | [Merck ]
14,352 | [Exposure limits]
NIOSH: TWA 2 mg/m3 | [InChIKey]
SWCIQHXIXUMHKA-UHFFFAOYSA-N | [LogP]
-0.129 (est) | [CAS DataBase Reference]
7784-27-2(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
O,Xi,Xn | [Risk Statements ]
R8:Contact with combustible material may cause fire.
R36/38:Irritating to eyes and skin .
R36:Irritating to the eyes.
R22:Harmful if swallowed. | [Safety Statements ]
S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 1438 5.1/PG 3
| [WGK Germany ]
1
| [RTECS ]
BD1050000
| [TSCA ]
Yes | [HazardClass ]
5.1 | [PackingGroup ]
III | [HS Code ]
28342980 | [Toxicity]
LD50 orally in Rabbit: 3671 mg/kg |
| Questions And Answer | Back Directory | [Uses]
The nonahydrate and other hydrated aluminum nitrates have many applications. These salts are used to produce alumina for preparation of insulating papers, in cathode tube heating elements, and on transformer core laminates. The hydrated salts are also used for extraction of actinide elements.
| [Preparation]
The nonahydrate is prepared by treating aluminum, aluminum hydroxide,
aluminum oxide, or aluminous mineral with nitric acid. The nitrate is crystallized from the solution. | [Reactions]
Since Al(NO3)3 or its salt hydrates dissociates to Al3+ and NO3– ions in the aqueous solution, its reactions in solutions are those of Al3+ . It is partially hydrolyzed, producing H3O+ and thus accounting for the acidity of its solution in water. The products constitute a complex mixture of mono- and polynuclear hydroxo species. Aluminum nitrate is soluble in bases, forming aluminates, [Al(OH)4(H2O)2]–. It decomposes to Al2O3 when heated at elevated temperatures.
|
| Hazard Information | Back Directory | [Chemical Properties]
Aluminium nitrate nonahydrate is white crystalline powder
| [Purification Methods]
Crystallise the nitrate from dilute HNO3, and dry it by passing dry nitrogen through the crystals for several hours at 40o. After 2 recrystallisations of ACS grade, it had S, Na and Fe at 2.2, 0.01 and 0.02 ppm, respectively. |
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