| Identification | More | [Name]
Allyl phenoxyacetate | [CAS]
7493-74-5 | [Synonyms]
2-PROPENYLPHENOXYACETATE
ACETATE PA
ALLYL PHENOXYACETATE
FEMA 2038
Acetic acid, phenoxy-, 2-propenyl ester
Acetic acid, phenoxy-, allyl ester
Aceticacid,phenoxy-,2-propenylester
phenoxy-aceticaci2-propenylester
phenoxy-aceticaciallylester
ALLYL PHENOXYACETATE 99+%
Allylphenoxyacetat
KAMILLENESTER
Phenoxyacetic Acid Allyl Ester
Prop-2-enyl 2-(phenoxy)acetate
ALLYL PHENOXYACETATE, 98+% | [EINECS(EC#)]
231-335-2 | [Molecular Formula]
C11H12O3 | [MDL Number]
MFCD00044632 | [Molecular Weight]
192.21 | [MOL File]
7493-74-5.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID | [Boiling point ]
265-266 °C(lit.) | [density ]
1.102 g/mL at 25 °C(lit.)
| [vapor pressure ]
7Pa at 20℃ | [FEMA ]
2038 | [refractive index ]
n20/D 1.516(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
neat | [color ]
Colorless to Almost colorless | [Odor]
at 100.00 %. sweet fresh honey pineapple chamomile cocoa | [biological source]
synthetic | [Odor Type]
fruity | [Water Solubility ]
practically insoluble | [JECFA Number]
18 | [LogP]
2.33 at 24.7℃ | [Uses]
Allyl Phenoxyacetate is a synthetic flavoring agent that is a stable,
colorless to light yellow liquid of heavy fruit note odor. it should be
stored in glass or tin containers. it is used in pineapple, quince, and
fruit flavors with applications in candy and beverages at 1–3 ppm. | [CAS DataBase Reference]
7493-74-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Allyl phenoxyacetate(7493-74-5) | [EPA Substance Registry System]
7493-74-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
1
| [RTECS ]
AJ2240000
| [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29189900 | [Safety Profile]
Moderately toxic by ingestion and skin contact. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLK COMPOUNDS.
| [Toxicity]
The acute oral LD50 value in rats was reported as 0.475 ml/kg . The acute dermal LD50 in rabbits was reported as 0.82 ml/kg. |
| Hazard Information | Back Directory | [Chemical Properties]
Allyl phenoxyacetate is a clear, colorless to
yellowish liquid with a green, sweet, herbal, fruity odor with nuances of galbanum
and pineapple.
It is prepared by reaction of phenoxyacetic acid alkali salts with allyl halogenide
and used in technical perfumery. | [Occurrence]
Has apparently not been reported to occur in nature. | [Definition]
ChEBI:Allyl phenoxyacetate is a monocarboxylic acid. | [Preparation]
By direct esterification in benzene solution.
| [Production Methods]
Allyl phenoxyacetate can be producted by direct esterification of Allyl alcohol
with Phenoxy acetic acid under azeotropic
conditions. | [Flammability and Explosibility]
Notclassified |
| Questions And Answer | Back Directory | [Aroma]
Somewhat sharp, mixed-fruity, mainly Pineapple-like and honey-sweet odor of great tenacity. Heavy-sweet fruity-honey-like taste, somewhat reminiscent of "cooked" fruit.
Rarely, if ever, used in perfumery, except for "honey" bases, etc. Used in flavor compositions, as a modifier in imitation Strawberry, Pineapple, etc. in mere traces. |
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