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ChemicalBook--->CAS DataBase List--->7460-82-4

7460-82-4

7460-82-4 Structure

7460-82-4 Structure
IdentificationMore
[Name]

DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)
[CAS]

7460-82-4
[Synonyms]

2,2'-OXYDIETHYL DITOSYLATE
BIS[2-(P-TOLUENESULFONYLOXY)ETHYL] ETHER
BIS(2-TOSYLOXYETHYL) ETHER
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)
DI(ETHYLENE GLYCOL) DI-P-TOSYLATE
DIETHYLENE GLYCOL DITOSYLATE
LABOTEST-BB LTBB005438
Diethylene glycol di(p-toluenesulfonate)
DEGditosylate
2,2-OXYBISETHANEBIS(4-METHYLBENZENESULFONATE)
2,2''-OXYDIETHYL BIS-(4-TOLUENESULFONATE)
2,2μ-Oxydiethyl ditosylate, Bis(2-tosyloxyethyl)ether, Diethylene glycol ditosylate
1,5-Bis(tosyloxy)-3-oxapentane
1,7-Ditosyl-1,4,7-trioxaheptane
Bis(4-methylbenzenesulfonic acid)3-oxa-1,5-pentanediyl
Bis(4-methylbenzenesulfonic acid)oxybisethylene ester
Bis(p-toluenesulfonic acid)(oxybisethylene) ester
[EINECS(EC#)]

628-596-3
[Molecular Formula]

C18H22O7S2
[MDL Number]

MFCD00026001
[Molecular Weight]

414.49
[MOL File]

7460-82-4.mol
Chemical PropertiesBack Directory
[Melting point ]

87-89 °C (lit.)
[Boiling point ]

581.2±45.0 °C(Predicted)
[density ]

1.301±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Chloroform (Slightly), Ethyl Acetate (Slightly)
[form ]

Solid
[color ]

Off-White
[BRN ]

583800
[InChIKey]

VYVPNTJBGPQTFA-UHFFFAOYSA-N
[CAS DataBase Reference]

7460-82-4(CAS DataBase Reference)
[EPA Substance Registry System]

Ethanol, 2,2'-oxybis-, bis(4-methylbenzenesulfonate) (7460-82-4)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[HS Code ]

2909.30.6000
Hazard InformationBack Directory
[Description]

Tos-PEG3-Tos is a PEG linker containing two tosyl groups. The hydrophilic PEG spacer increases solubility in aqueous media. The tosyl group is a very good leaving group for nucleophilic substitution reactions.
[Chemical Properties]

White to off-white powder
[Uses]

Diethylene glycol di(p-toluenesulfonate) was used in the synthesis of bis(dibenzosulfoxo)-27,30,35,38-tetramethyl-24-crown-6, bis(dibenzosulfoxo)-21,24,29,32-tetramethyl-18-crown-4, dibenzosulfoxo-15,18-dimethyl-12-crown-3 and dibenzosulfoxo-12,15-dimethyl-9-crown-2 macrocycles.
[Purification Methods]

Purify the ester by recrystallisation from Me2CO and dry it in a vacuum. [Beilstein 11 III 225.]
Spectrum DetailBack Directory
[Spectrum Detail]

DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)(7460-82-4)MS
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)(7460-82-4)1HNMR
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)(7460-82-4)13CNMR
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)(7460-82-4)IR1
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)(7460-82-4)IR2
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)(7460-82-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

7460-82-4(sigmaaldrich)
[TCI AMERICA]

Diethylene Glycol Bis(p-toluenesulfonate),>95.0%(LC)(T)(7460-82-4)
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