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ChemicalBook--->CAS DataBase List--->624-24-8

624-24-8

624-24-8 Structure

624-24-8 Structure
IdentificationMore
[Name]

METHYL VALERATE
[CAS]

624-24-8
[Synonyms]

C5
FEMA 2752
METHYL N-PENTANOATE
METHYL N-VALERATE
METHYL PENTANOATE
METHYL VALERATE
N-VALERIC ACID METHYL ESTER
PENTANOIC ACID METHYL ESTER
RARECHEM AL BF 0163
VALERIC ACID METHYL ESTER
CH3(CH2)3COOCH3
Methyl ester of pentanoic acid
Methyl valerianate
methylvalerianate
METHYL VALERATE 99+%
METHYL VALERATE OEKANAL
METHYL VALERATE MIN. 99,9 % FOR GAS CHRO MATOGRAPHY
METHYL VALERATE, STANDARD FOR GC
METHYL VALERATE GC STANDARD
Methylvalerat
[EINECS(EC#)]

210-838-0
[Molecular Formula]

C6H12O2
[MDL Number]

MFCD00009478
[Molecular Weight]

116.16
[MOL File]

624-24-8.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Melting point ]

-91°C
[Boiling point ]

128 °C (lit.)
[density ]

0.875 g/mL at 25 °C(lit.)
[vapor pressure ]

19.33hPa at 20℃
[FEMA ]

2752
[refractive index ]

n20/D 1.397(lit.)
[Fp ]

72 °F
[storage temp. ]

Flammables area
[solubility ]

5g/l
[form ]

Liquid
[color ]

Clear colorless
[Specific Gravity]

0.892 (20/4℃)
[Odor]

at 1.00 % in dipropylene glycol. sweet green fruity apple pineapple nutty
[Odor Threshold]

0.0022ppm
[Odor Type]

fruity
[Water Solubility ]

3.5g/L at 20℃
[JECFA Number]

159
[BRN ]

1741905
[Dielectric constant]

4.3(19℃)
[LogP]

2.25 at 25℃
[CAS DataBase Reference]

624-24-8(CAS DataBase Reference)
[EPA Substance Registry System]

Methyl valerate (624-24-8)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R10:Flammable.
R20:Harmful by inhalation.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S7/9:Keep container tightly closed and in a well-ventilated place .
[RIDADR ]

UN 3272 3/PG 2
[WGK Germany ]

2
[RTECS ]

YV7750500
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29156000
Hazard InformationBack Directory
[General Description]

Clear colorless to yellowish oily liquid.
[Reactivity Profile]

METHYL VALERATE(624-24-8) is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. This compound reacts with oxidizing agents, bases and acids.
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Fire Hazard]

This chemical is flammable.
[Description]

Methyl pentanoate, commonly known as methyl valerate, is the methyl ester of pentanoic acid (valeric acid) with a fruity odor.
Methyl pentanoate is commonly used in fragrances, beauty care, soap, laundry detergents at levels of 0.1 – 1 % .
In a very pure form ( greater than 99.5 % ) it is used as a plasticizer in the manufacture of plastics.
It is also used as an insecticide.
[Chemical Properties]

clear colorless liquid
[Chemical Properties]

Methyl valerate has a pungent, green-fruity odor that is apple- and pineapple-like with a corresponding flavor at 1 0 - 5 0 ppm. May be prepared by direct esterification of the valeric acid with methanol in the presence of concentrated H2S04; note: this ester hydrolyzes readily.
[Chemical Properties]

Methyl valerate has a pungent, green-fruity odor, apple and pineapple-like. It has a similar flavor at 10 to 50 ppm
[Occurrence]

Reported found in small amounts in the essential oil from the fruits of Ananas sativus Schult. Also reported present in apple, coffee, honey, kiwi, melon, papaya, pineapple, strawberry, tea, wine, blackberry, baked potato, olive, starfruit, passion fruit, soursop, Bourbon vanilla, mountain papaya and naranjilla fruit.
[Uses]

Methyl valerate can be used:
  • In the preparation of lankacidin C 8-valerate.
  • As a reactant to synthesize bis(2,2,2-trifluoroethyl) 2-oxoalkylphosphonates.
  • As a substrate in the fluorination reactions of unactivated C(sp3)H bonds using decatungstate photocatalyst and N-fluorobenzenesulfonimide.

[Preparation]

By direct esterification of valeric acid with methanol in the presence of concentrated H2SO4. Note: This ester hydrolyzes readily
[Aroma threshold values]

Detection: 20 to 89 ppb
[Taste threshold values]

Taste characteristics at 20 ppm: sweet, ripe, fruity with sweaty, dairy and cheesy nuance
[Synthesis Reference(s)]

Journal of the American Chemical Society, 97, p. 1180, 1975 DOI: 10.1021/ja00838a036
[Flammability and Explosibility]

Flammable
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

methyl n-valerate(624-24-8).msds
Spectrum DetailBack Directory
[Spectrum Detail]

METHYL VALERATE(624-24-8)MS
METHYL VALERATE(624-24-8)1HNMR
METHYL VALERATE(624-24-8)13CNMR
METHYL VALERATE(624-24-8)IR1
METHYL VALERATE(624-24-8)IR2
METHYL VALERATE(624-24-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl valerate, 99%(624-24-8)
[Alfa Aesar]

Methyl valerate, 99%(624-24-8)
[Sigma Aldrich]

624-24-8(sigmaaldrich)
[TCI AMERICA]

Methyl Valerate,>99.0%(GC)(624-24-8)
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