| Identification | More | [Name]
(S)-Oxiranemethanol | [CAS]
60456-23-7 | [Synonyms]
[(2r)-oxiran-2-yl]methanol
OXIRANEMETHANOL, (2S)-
(r)-3-hydroxy-1,2-epoxypropane
RARECHEM AK HZ 0047
(S)-(-)-2,3-EPOXY-1-PROPANOL
(S)-(-)-GLYCIDOL
(S)-GLYCIDOL
S(-)-OXIRANE-2-METHANOL
(S)-Oxiranemethanol
(s)-oxiranemethano
Oxiranemethanol,(S)-
(S)-(-)-GLYCIDOL, 97% (98% EE/GLC)
S-Glycidoe
(R)-3-Hydroxy-1,2-epoxypropane
(S)-(-)-GLYCIDOL ((S)-(-)-2,3-EPOXY-1-PROPANOL)
(S)-(-)-2,3-Epoxy-1-propanol, (S)-(-)-Oxirane-2-methanol | [Molecular Formula]
C3H6O2 | [MDL Number]
MFCD00074874 | [Molecular Weight]
74.08 | [MOL File]
60456-23-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [Melting point ]
72-73 °C | [alpha ]
-15 º (neat) | [Boiling point ]
66-67 °C19 mm Hg(lit.) | [density ]
1.116 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.433(lit.)
| [Fp ]
178 °F
| [storage temp. ]
−20°C
| [solubility ]
Soluble in chloroform, DMSO and methanol. | [form ]
Liquid | [pka]
14.62±0.10(Predicted) | [color ]
Pale yellow | [optical activity]
[α]20/D 15°, neat | [BRN ]
79783 | [InChIKey]
CTKINSOISVBQLD-VKHMYHEASA-N | [CAS DataBase Reference]
60456-23-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Oxiranemethanol, (S)-(60456-23-7) |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R45:May cause cancer.
R60:May impair fertility.
R21/22:Harmful in contact with skin and if swallowed .
R23:Toxic by inhalation.
R36/37/38:Irritating to eyes, respiratory system and skin .
R68:Possible risk of irreversible effects.
R41:Risk of serious damage to eyes.
R37/38:Irritating to respiratory system and skin . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 2810 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
RR0508100
| [F ]
10-21 | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29109000 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
Employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis. | [Definition]
ChEBI: (S)-glycidol is a glycidol. It is functionally related to a (S)-1,2-epoxypropane. It is an enantiomer of a (R)-glycidol. | [General Description]
Glycidol or 2,3-epoxy-1-propanol is a highly reactive epoxy derivative, which is generally used as a monomer in the preparation of many polymers like polyesters,?polycarbonates,?polyurethanes,?and polyamides. It is also used in the preparation of detergents, rubbers, perfumes, fabric dyes, varnishes, cosmetics, and paints. | [Purification Methods]
[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation. |
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