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ChemicalBook--->CAS DataBase List--->598-21-0

598-21-0

598-21-0 Structure

598-21-0 Structure
IdentificationMore
[Name]

Bromoacetyl bromide
[CAS]

598-21-0
[Synonyms]

2-BROMOACETYL BROMIDE
AKOS BBS-00004286
BROMOACETIC ACID BROMIDE
BROMOACETYL BROMIDE
Acetyl bromide, bromo-
acetylbromide,bromo-
bromoacetyl
bromo-acetylbromid
BROMOACETYL BROMIDE, 98+%
ALPHA-BROMOACETYL BROMIDE
A-BROMOACETYL BROMIDE
Monobromoacetyl bromide
1,2-Dibromoethanone
[EINECS(EC#)]

209-923-5
[Molecular Formula]

C2H2Br2O
[MDL Number]

MFCD00000115
[Molecular Weight]

201.84
[MOL File]

598-21-0.mol
Chemical PropertiesBack Directory
[Appearance]

dark brown-yellow liquid
[Melting point ]

148.5°C (estimate)
[Boiling point ]

147-150 °C(lit.)
[density ]

2.324 g/mL at 20 °C
[vapor pressure ]

3.8 mm Hg ( 25 °C)
[refractive index ]

n20/D 1.547(lit.)
[Fp ]

>105°C
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

soluble in Chloroform
[form ]

Powder
[color ]

White
[Stability:]

Stable, but reacts violently with water. Incompatible with water, moisture, alcohols, strong bases, strong oxidizing agents.
[Water Solubility ]

REACTS
[Sensitive ]

Moisture Sensitive
[Detection Methods]

GC
[BRN ]

605440
[Dielectric constant]

12.6(20℃)
[InChIKey]

LSTRKXWIZZZYAS-UHFFFAOYSA-N
[LogP]

-0.04 at 25℃
[CAS DataBase Reference]

598-21-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Bromoacetyl bromide(598-21-0)
[EPA Substance Registry System]

598-21-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R14:Reacts violently with water.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S8:Keep container dry .
S30:Never add water to this product .
S25:Avoid contact with eyes .
[RIDADR ]

UN 2513 8/PG 2
[WGK Germany ]

3
[F ]

10-19
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29159080
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Phosphorus
[Preparation Products]

6-BROMO-2H-1,4-BENZOXAZIN-3(4H)-ONE-->2-Hydrazinyl-1-(4-methylpiperazin-1-yl)ethanone-->2-Hydrazinyl-1-morpholinoethanone-->2-(4-PENTYLBENZOYL)-1-BENZOFURAN-5-CARBALDEHYDE-->DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE-->Clonazepam-->Benzyl bromide-->N-Benzylglycine-->7-(ALPHA-BROMOACETAMIDO)CEPHALOSPORANIC ACID-->5-Bromoacetyl-2-hydroxybenzaldehyde-->Phenyl bromoacetate-->Glycine, N-(phenylMethyl)-, Methyl ester-->2-Bromo-4'-hydroxyacetophenone-->2-broMo-N-Methyl-N-(4-nitrophenyl)acetaMide-->2-bromo-N,N-dibutylacetamide-->2-Bromo-2',4'-difluoroacetophenone-->N,N'-ethylidenebis(2-bromoacetamide)-->3,5-BIS(TRIFLUOROMETHYL)-N-(BROMOACETYL)ANILINE-->N-(1-benzylpiperidin-4-yl)-2-bromoacetamide(SALTDATA: 0.35HCl)-->2-BROMO-N-(3-CHLORO-PHENYL)-ACETAMIDE-->3-(BROACETYL)AMINOPHENOL
Hazard InformationBack Directory
[General Description]

A water-white liquid with a pungent odor. Denser than water. Irritates skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.
[Reactivity Profile]

BROMOACETYL BROMIDE(598-21-0) is incompatible with water, with bases (including amines), with strong oxidizing agents, with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Decomposes when heated with evolution of highly toxic and irritating hydrogen bromide and bromophosgene vapors.
[Air & Water Reactions]

Fumes in air. Reacts violently with water to form hydrobromic acid (HBr) (USCG 1991).
[Health Hazard]

Inhalation causes severe irritation of upper respiratory system. External contact causes severe irritation of eyes and skin. Ingestion causes severe irritation of mouth and stomach.
[Chemical Properties]

dark brown-yellow liquid
[Uses]

Bromoacetyl bromide is widely used in the synthesis of fine chemicals, agrochemicals, dyes and pharmaceuticals. As an acylating agent, it reacts with 10H-phenothiazine to give 10-bromoacetyl-10H-phenothiazine. Similarly, it is also involved in the preparation of bromoactylated starch which is a biodegradable thermoplastic copolymer.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Bromoacetyl bromide(598-21-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Bromoacetyl bromide(598-21-0)MS
Bromoacetyl bromide(598-21-0)1HNMR
Bromoacetyl bromide(598-21-0)13CNMR
Bromoacetyl bromide(598-21-0)IR1
Bromoacetyl bromide(598-21-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Bromoacetyl bromide, 98+%(598-21-0)
[Alfa Aesar]

Bromoacetyl bromide, 98%(598-21-0)
[Sigma Aldrich]

598-21-0(sigmaaldrich)
[TCI AMERICA]

Bromoacetyl Bromide,>98.0%(GC)(T)(598-21-0)
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