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ChemicalBook--->CAS DataBase List--->586-96-9

586-96-9

586-96-9 Structure

586-96-9 Structure
IdentificationBack Directory
[Name]

Nitrosobenzene
[CAS]

586-96-9
[Synonyms]

nob
Nitrosobenzol
NITROSOBENZENE
nitroso-benzen
benzene,nitroso-
1-Nitrosobenzene
Nitrosobenzene,NOB
Nitrosobenzene >=97%
[EINECS(EC#)]

209-591-1
[Molecular Formula]

C6H5NO
[MDL Number]

MFCD00002059
[MOL File]

586-96-9.mol
[Molecular Weight]

107.11
Chemical PropertiesBack Directory
[Appearance]

light yellow solid
[Melting point ]

65-69 °C(lit.)
[Boiling point ]

59 °C18 mm Hg(lit.)
[density ]

1.1697 (rough estimate)
[refractive index ]

1.5389 (estimate)
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

Solid
[color ]

White to Brown
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[BRN ]

605688
[InChIKey]

NLRKCXQQSUWLCH-UHFFFAOYSA-N
[CAS DataBase Reference]

586-96-9
[NIST Chemistry Reference]

Benzene, nitroso-(586-96-9)
[EPA Substance Registry System]

Nitrosobenzene (586-96-9)
Hazard InformationBack Directory
[Chemical Properties]

light yellow solid
[Uses]

Spin trap reagent. Has been used in the study of oxidative DNA damage and nitroso-compound-induced respiratory burst in neutrophils3,4.
[Definition]

ChEBI: A nitroso compound that is the nitroso derivative of benzene; a diamagnetic hybrid of singlet O2 and azobenzene.
[storage]

Store at -20°C
[Purification Methods]

Steam distil nitrosobenzene, then crystallise it from a small volume of EtOH with cooling below 0o, dry it over CaCl2 in a dessicator at atmospheric pressure, and store it under N2 at 0o. Alternatively it can be distilled onto a cold finger cooled with brine at ~-10o in a vacuum at 17mm (water pump), while heating in a water bath at 65-70o [Robertson & Vaughan J Chem Educ 27 605 1950]. [Beilstein 5 IV 702.]
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

20/21-25
[Safety Statements ]

26-36/37-45
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

DA6497525
[F ]

9-23
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29042000
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Nitrosobenzene(586-96-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Nitrosobenzene(586-96-9)1HNMR
Nitrosobenzene(586-96-9)13CNMR
Nitrosobenzene(586-96-9)IR1
Nitrosobenzene(586-96-9)IR2
Nitrosobenzene(586-96-9)Raman
Nitrosobenzene(586-96-9)ESR
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