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ChemicalBook--->CAS DataBase List--->540-80-7

540-80-7

540-80-7 Structure

540-80-7 Structure
IdentificationMore
[Name]

tert-Butyl nitrite
[CAS]

540-80-7
[Synonyms]

α,α-Dimethylethyl nitrite
NITROUS ACID TERT-BUTYL ESTER
T-BUTYL NITRITE
TERT-BUTYL NITRITE
TIMTEC-BB SBB007659
1,1-dimethylethylnitrite
2-methyl-2-nitritopropane
alpha,alpha-Dimethylethyl nitrite
alpha,alpha-dimethylethylnitrite
Nitrous acid, 1,1-dimethylethyl ester
Nitrous acid, t-butyl ester
nitrousacid,1,1-dimethylethylester
nitrousacid,t-butylester
tert-Butylnitrite,tech.90%
tert-Butyl nitrite, pure, 90%
t-Buthyl nitrite
2-methyl-2-propyl nitrite
TERT-BUTYL NITRITE: TECH., 90%
tert-Butyl nitrite, 90%, pure
Nitrous acid tert-butyl
[EINECS(EC#)]

208-757-0
[Molecular Formula]

C4H9NO2
[MDL Number]

MFCD00002055
[Molecular Weight]

103.12
[MOL File]

540-80-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow liquid
[Boiling point ]

61-63 °C(lit.)
[density ]

0.867 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.368(lit.)
[Fp ]

−10 °F
[storage temp. ]

2-8°C
[solubility ]

alcohol: very soluble(lit.)
[form ]

Liquid
[color ]

Clear yellow
[Water Solubility ]

slightly soluble
[Merck ]

14,1583
[BRN ]

1209339
[CAS DataBase Reference]

540-80-7(CAS DataBase Reference)
[NIST Chemistry Reference]

(CH3)3CONO(540-80-7)
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

R11:Highly Flammable.
R20/22:Harmful by inhalation and if swallowed .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S24:Avoid contact with skin .
S46:If swallowed, seek medical advice immediately and show this container or label .
[RIDADR ]

UN 2351 3/PG 2
[WGK Germany ]

1
[RTECS ]

RA0802000
[F ]

8
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29209085
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2-Chloro-2-methylpropane-->Silver nitrate-->NITRIC OXIDE-->Nitrogen Tetroxide-->Benzyln-butylether-->tert-butoxy-->TERT-BUTYL NITRATE-->2-Methyl-2-nitropropane-->tert-Butanol-->tert-Butyl hydroperoxide-->3,3-dimethylbutanal-->2-Bromo-2-methylpropane
[Preparation Products]

2-Chloro-5-cyano-3-methylpyridine-->2-Bromo-5-hydroxypyridine radical ion(1+)-->2-Bromo-5-fomylthiazole-->2-CHLORO-5-IODO-3-METHYLPYRIDINE-->4,7-DIHYDRO-4-OXO-3H-PYRROLO[2,3-D][1,2,3]TRIAZINE-5-CARBOXAMIDE-->8-Quinolineboronic acid-->Goserelin-->2,6-Dibromoanthraquinone-->3,5-Diiodobenzoic acid-->4-CHLORO-2-NITROPHENOL-->tert-butyl 2-bromo-6,7-dihydrothiazolo[5,4-c]pyridine-5(4H)-carboxylate-->S-NITROSOGLUTATHIONE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

tert-Butyl nitrite(540-80-7).msds
Hazard InformationBack Directory
[Chemical Properties]

clear yellow liquid
[Uses]

Jet propellant.
[General Description]

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.
[Purification Methods]

If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]
Spectrum DetailBack Directory
[Spectrum Detail]

tert-Butyl nitrite(540-80-7)MS
tert-Butyl nitrite(540-80-7)1HNMR
tert-Butyl nitrite(540-80-7)13CNMR
tert-Butyl nitrite(540-80-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

tert-Butyl nitrite, pure, 90%(540-80-7)
[Alfa Aesar]

tert-Butyl nitrite, tech. 90%(540-80-7)
[Sigma Aldrich]

540-80-7(sigmaaldrich)
[TCI AMERICA]

tert-Butyl Nitrite,>90.0%(GC)(540-80-7)
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