| Identification | More | [Name]
2-Bromo-4-methylaniline | [CAS]
583-68-6 | [Synonyms]
2-BROMO-4-METHYLANILINE
2-BROMO-4-METHYL-PHENYLAMINE
2-BROMO-P-TOLUIDINE
3-BROMO-4-AMINOTOLUENE
4-AMINO-3-BROMOTOLUENE
4-AMINO-3-BROMTOLUOL
AKOS BBS-00003652
2-bromo-4-methyl-benzenamin
2-Bromo-4-methylbenzenamine
2-Bromo-4-toluidine
2-bromo-p-toluidin
2-bromotoluidine
4-methyl-2-bromoaniline
o-Bromo-p-toluidine
p-Toluidine, 2-bromo-
2-Bromo-4-methylaniline, (4-Amino-3-bromotoluene
2-Bromo-4-methylaniline,99% (4-Amino-3-bromtoluol)
2-Bromo-p-toluid
4-Amino-3-bromotoluene~2-Bromo-p-toluidine
2-Bromo-4-methylanline | [EINECS(EC#)]
209-515-7 | [Molecular Formula]
C7H8BrN | [MDL Number]
MFCD00007635 | [Molecular Weight]
186.05 | [MOL File]
583-68-6.mol |
| Chemical Properties | Back Directory | [Appearance]
clear light yellow to brown liquid | [Melting point ]
14-16 °C (lit.) | [Boiling point ]
240 °C (lit.) | [density ]
1.5 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.602(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Slightly) | [form ]
Oil | [pka]
2.97±0.10(Predicted) | [color ]
Dark Yellow to Dark Beige | [Specific Gravity]
1.500 | [Water Solubility ]
Insoluble in water. | [BRN ]
1931711 | [Stability:]
Air Sensitive | [InChIKey]
UVRRJILIXQAAFK-UHFFFAOYSA-N | [CAS DataBase Reference]
583-68-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenamine, 2-bromo-4-methyl-(583-68-6) | [EPA Substance Registry System]
583-68-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R33:Danger of cumulative effects.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
XU4300000
| [Hazard Note ]
Irritant/Toxic | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29214300 |
| Hazard Information | Back Directory | [Chemical Properties]
clear light yellow to brown liquid | [Uses]
2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes. | [General Description]
2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide. |
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