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ChemicalBook--->CAS DataBase List--->57044-25-4

57044-25-4

57044-25-4 Structure

57044-25-4 Structure
IdentificationMore
[Name]

(R)-(+)-Glycidol
[CAS]

57044-25-4
[Synonyms]

OXIRANEMETHANOL, (2R)-
(R)-(+)-2,3-EPOXY-1-PROPANOL
(R)-(+)-GLYCIDOL
(R)-GLYCIDOL
R(+)-OXIRANE-2-METHANOL
(R)-Oxiranemethanol
(r)-oxiranemethano
(R)-(+)-GLYCIDOL, 97% (98% EE/GLC)
R-Glycidoe
(R)-GLYCIDOL,99%
(R)-3-Hydroxy-1,2-epoxypropane
(R)-(+)-GLYCIDOL ((R)-(+)-2,3-EPOXY-1-PROPANOL)
(2R)-Oxirane-2-methanol
(R)-2-Hydroxymethyloxirane
[EINECS(EC#)]

404-660-4
[Molecular Formula]

C3H6O2
[MDL Number]

MFCD00074873
[Molecular Weight]

74.08
[MOL File]

57044-25-4.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Boiling point ]

56-57 °C11 mm Hg(lit.)
[density ]

1.116 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.43(lit.)
[Fp ]

178 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), DMSO (Slightly)
[Water Solubility ]

Completely miscible in water
[form ]

neat
[pka]

14.62±0.10(Predicted)
[color ]

Colorless to Light yellow
[optical activity]

[α]23/D +15°, neat
[BRN ]

79782
[Stability:]

Moisture Sensitive
[InChIKey]

CTKINSOISVBQLD-GSVOUGTGSA-N
[CAS DataBase Reference]

57044-25-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Oxiranemethanol, (R)-(57044-25-4)
Safety DataBack Directory
[Hazard Codes ]

T,E
[Risk Statements ]

R45:May cause cancer.
R60:May impair fertility.
R2:Risk of explosion by shock, friction, fire or other sources of ignition.
R21/22:Harmful in contact with skin and if swallowed .
R23:Toxic by inhalation.
R34:Causes burns.
R68:Possible risk of irreversible effects.
R41:Risk of serious damage to eyes.
R37/38:Irritating to respiratory system and skin .
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 2922 8/PG 2
[WGK Germany ]

3
[RTECS ]

RR0508000
[F ]

10-21
[HazardClass ]

6.1
[PackingGroup ]

[HS Code ]

29109000
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

(S)-(+)-Methyl glycidyl ether-->(S)-(+)-Glycidyl butyrate-->1,2-Propanediol, 3-(dodecyloxy)-, (2R)--->(S)-2-((2-FLUOROPHENOXY)METHYL)OXIRANE
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

(R)-(+)-Glycidol may be used in the following synthesis:
  • heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
  • enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
  • 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
  • (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
  • 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
  • chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product
[Definition]

ChEBI: (R)-glycidol is a glycidol. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (S)-glycidol.
[General Description]

Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.
[Purification Methods]

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-(+)-Glycidol(57044-25-4)FT-IR
(R)-(+)-Glycidol(57044-25-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

57044-25-4(sigmaaldrich)
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