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ChemicalBook--->CAS DataBase List--->55289-35-5

55289-35-5

55289-35-5 Structure

55289-35-5 Structure
IdentificationMore
[Name]

2-Bromo-6-nitrotoluene
[CAS]

55289-35-5
[Synonyms]

1-BROMO-2-METHYL-3-NITROBENZENE
2-BROMO-6-NITROTOLUENE
2-BROMO-6-NITROTOLUENE,2-NITRO-6-BROMOTOLUENE
6-BROMO-2-NITROTOLUENE
Toluene, 2-bromo-6-nitro-
2-BROMO-6-NITROTOLUENE 98+%
1-Methyl-2-bromo-6-nitrobenzene
1-Nitro-2-methyl-3-bromobenzene
2-Methyl-3-nitrophenyl bromide
[EINECS(EC#)]

259-566-4
[Molecular Formula]

C7H6BrNO2
[MDL Number]

MFCD00009792
[Molecular Weight]

216.03
[MOL File]

55289-35-5.mol
Chemical PropertiesBack Directory
[Melting point ]

38-40 °C (lit.)
[Boiling point ]

143 °C/22 mmHg (lit.)
[density ]

1.6841 (rough estimate)
[refractive index ]

1.6120 (estimate)
[Fp ]

>110°C
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Low Melting Solid
[color ]

Slightly beige to brown
[BRN ]

2502581
[CAS DataBase Reference]

55289-35-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-bromo-2-methyl-3-nitro-(55289-35-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 2810 6.1/PG 1
[WGK Germany ]

3
[HS Code ]

29049090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

4-BROMOOXINDOLE-->2-amino-4-bromo-3-methylbenzoic acid-->2-BROMO-5-NITROTOLUENE-->4-Bromo-2-nitrotoluene-->3-Amino-2-methylphenylboronic acid, pinacol ester-->4-broMo-3-Methylbenzene-1,2-diaMine-->1-broMo-2-(broMoMethyl)-3-nitrobenzene-->2-Bromo-6-nitrobenzoic acid-->6-Bromoisatinic anhydride-->Ethyl 3-(2-BroMo-6-nitrophenyl)-2-oxopropanoate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Bromo-2-methyl-3-nitrobenzene(55289-35-5).msds
Hazard InformationBack Directory
[Chemical Properties]

Beige solid
[Uses]

2-Bromo-6-nitrotoluene has been used:
  • as starting reagent in total synthesis of N-acetyl methyl ester of (±)-clavicipitic acids
  • in synthesis of carbazomadurin A, highly oxygenated neuronal cell protecting carbazole alkaloid
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 49, p. 2657, 1984 DOI: 10.1021/jo00189a001
Spectrum DetailBack Directory
[Spectrum Detail]

2-Bromo-6-nitrotoluene(55289-35-5)MS
2-Bromo-6-nitrotoluene(55289-35-5)1HNMR
2-Bromo-6-nitrotoluene(55289-35-5)13CNMR
2-Bromo-6-nitrotoluene(55289-35-5)IR1
2-Bromo-6-nitrotoluene(55289-35-5)IR2
2-Bromo-6-nitrotoluene(55289-35-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-Bromo-6-nitrotoluene, 98%(55289-35-5)
[Sigma Aldrich]

55289-35-5(sigmaaldrich)
[TCI AMERICA]

2-Bromo-6-nitrotoluene,>98.0%(GC)(55289-35-5)
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