Identification | More | [Name]
9-Bromo-9-phenylfluorene | [CAS]
55135-66-5 | [Synonyms]
9-BROMO-9-PHENYL-9H-FLUORENE 9-BROMO-9-PHENYLFLUORENE AKOS 91526 9-Bromo-9-phenylfluorene,97% | [EINECS(EC#)]
628-283-1 | [Molecular Formula]
C19H13Br | [MDL Number]
MFCD00075522 | [Molecular Weight]
321.21 | [MOL File]
55135-66-5.mol |
Chemical Properties | Back Directory | [Appearance]
Yellow Crystalline Solid | [Melting point ]
99-101 °C (lit.) | [Boiling point ]
394.3±41.0 °C(Predicted) | [density ]
1.425±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [Usage]
A bulky amine protecting reagent reported to be 6000 times more stable to acid than the trityl group | [BRN ]
2561445 | [InChIKey]
HYQXNCDBSALQLB-UHFFFAOYSA-N | [CAS DataBase Reference]
55135-66-5(CAS DataBase Reference) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S27:Take off immediately all contaminated clothing . S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29039930 |
Hazard Information | Back Directory | [Chemical Properties]
Yellow Crystalline Solid | [Uses]
9-Bromo-9-phenylfluorene may be used in the preparation of:
- N-(9-(9-phenylfluorenyl))-L-alaninal
- N-(9-phenylfluoren-9-yl)-L-serine
- 1-hydroxypyrazoles priotected at the oxygen atom
| [Uses]
A bulky amine protecting reagent reported to be 6000 times more stable to acid than the trityl group | [General Description]
Solvolysis of 9-bromo-9- phenylfluorene has been reported to proceed via limiting SN1 mechanism. |
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