| Identification | More | [Name]
Benzyl 2-bromoacetate | [CAS]
5437-45-6 | [Synonyms]
2-BROMO-ACETIC ACID BENZYLESTER
BENZYL 2-BROMOACETATE
BENZYL BROMOACETATE
BROMOACETIC ACID BENZYL ESTER
TIMTEC-BB SBB006752
Acetic acid, bromo-, benzyl ester
Acetic acid, bromo-, phenylmethyl ester
bromo-aceticacibenzylester
bromo-aceticaciphenylmethylester
merbac35
Benzyl-2-Bromoacetate96%
Benzylbromoacetate,97%
Benzyl a-Bromoacetate
bromo-acetic acid phenylmethyl ester
Bromoacetic acid benzyl este
Phenylmethyl 2-bromoacetate
Bromoacetic acid benzyl | [EINECS(EC#)]
226-611-4 | [Molecular Formula]
C9H9BrO2 | [MDL Number]
MFCD00000190 | [Molecular Weight]
229.07 | [MOL File]
5437-45-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [Melting point ]
199-201 °C(Solv: water (7732-18-5)) | [Boiling point ]
166-170 °C22 mm Hg(lit.) | [density ]
1.446 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.544(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Liquid | [color ]
Clear colorless to light yellow | [Specific Gravity]
1.446 | [Water Solubility ]
Not miscible or difficult to mix in water. | [BRN ]
973658 | [LogP]
2.368 (est) | [CAS DataBase Reference]
5437-45-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzyl 2-bromoacetate(5437-45-6) | [EPA Substance Registry System]
5437-45-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
2810 | [WGK Germany ]
3
| [RTECS ]
AF5957215
| [F ]
19 | [HS Code ]
29159080 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
It is employed in biological research purpose. Benzyl bromoacetate was used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid. | [Purification Methods]
Dilute the ester with Et2O, wash it with 10% aqueous NaHCO3, H2O, dry (MgSO4) and fractionate it using a Fenske (glass helices packing) column. [Bergmann & Szinai J Chem Soc 1521 1956, Beilstein 6 IV 2265.] LACHRYMATORY. |
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