Identification | More | [Name]
(R,R)-(+)-HYDROBENZOIN | [CAS]
52340-78-0 | [Synonyms]
(1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIOL (1R,2R)-(+)-HYDROBENZOIN (R,R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIOL (R,R)-1,2-DIPHENYL-1,2-ETHANEDIOL (R,R)-(+)-1,2-DIPHENYLETHANEDIOL (R,R)-1,2-DIPHENYL-ETHYLENE GLYCOL (R,R)-(+)-HYDROBENZOIN (R,R)-(+)-HYDROBENZOIN, 99% (99% EE/HPL& (R,R)-(+)-Hydrobenzoine (R,R)-(+)-1,2-Diphenyl-1,2-ethanediol, 98+% (1R,2R)-DIPHENYL-1,2-ETHANEDIOL/(R,R)-(+)-HYDROBENZOIN (R,R)-(+)-Hydrobenzoin, 98+% (R,R)-1,2-Diphenyl-1,2-ethanediol, (R,R)-1,2-Diphenylethylene glycol (1R,2R)-1,2-Diphenylethylene glycol (αR,βR)-Bibenzyl-α,β-diol | [Molecular Formula]
C14H14O2 | [MDL Number]
MFCD00064254 | [Molecular Weight]
214.26 | [MOL File]
52340-78-0.mol |
Chemical Properties | Back Directory | [Appearance]
white to beige or light brown crystalline powder | [Melting point ]
146-149 °C(lit.)
| [Boiling point ]
314.4°C (rough estimate) | [density ]
1.0781 (rough estimate) | [refractive index ]
95 ° (C=1, CHCl3) | [storage temp. ]
2-8°C
| [solubility ]
Soluble in DMSO | [form ]
Crystalline Powder or Crystals | [pka]
13.38±0.20(Predicted) | [color ]
White to beige or light brown | [optical activity]
[α]28/D +93°, c = 2.5 in ethanol | [Merck ]
4777 | [BRN ]
2050815 | [CAS DataBase Reference]
52340-78-0(CAS DataBase Reference) |
Safety Data | Back Directory | [Safety Statements ]
S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [F ]
10 | [HS Code ]
29062990 |
Hazard Information | Back Directory | [Chemical Properties]
white to beige or light brown crystalline powder | [Uses]
(R,R)-(+)-Hydrobenzoin may be used in the oxyselenenylation step in the multi-step synthesis of cyclopentitols and aminocyclopentitols from cyclopentene. It may also be used as a ligand for the asymmetric addition of diethylzinc to aldehydes in the presence or absence of titanium tetra-isopropoxide to form (R)- or (S)-form of the corresponding secondary alcohol, respectively. | [Definition]
ChEBI: (R,R)-hydrobenzoin is a hydrobenzoin. | [General Description]
(R,R)-(+)-Hydrobenzoin is a chiral 1,2-diol useful as a chiral reagent, building block, ligand or auxiliary in asymmetric synthesis. |
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