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ChemicalBook--->CAS DataBase List--->462-94-2

462-94-2

462-94-2 Structure

462-94-2 Structure
IdentificationMore
[Name]

1,5-Diaminopentane
[CAS]

462-94-2
[Synonyms]

1,5-DIAMINOPENTANE
1,5-PENTAMETHYLENEDIAMINE
1,5-PENTANEDIAMINE
5,5'-PENTANEDIAMINE
CADAVERINE
PENTAMETHYLENEDIAMINE
RARECHEM AL BW 0076
1,4-Pentanediamine
Animal coniine
animalconiine
Cadaverin
H2N(CH2)5NH2
Pentane-1,5-diamine
Cadavarine
CADAVERINE, APPROX. 98%
1,5-Diaminopentane,98%
CADAVERIN FREE BASE extrapure
1,5-Diaminopentane, 1,5-Pentanediamine, Pentamethylenediamine
1,5-Amylene diamine
1,5-Diamino-n-pentane
[EINECS(EC#)]

207-329-0
[Molecular Formula]

C5H14N2
[MDL Number]

MFCD00008239
[Molecular Weight]

102.18
[MOL File]

462-94-2.mol
Chemical PropertiesBack Directory
[Appearance]

colourless to light yellow liquid with a very unpleasant smell
[Melting point ]

9 °C
[Boiling point ]

178-180 °C(lit.)
[density ]

0.873 g/mL at 25 °C(lit.)
[vapor pressure ]

1.29-17hPa at 20-25℃
[refractive index ]

n20/D 1.458(lit.)
[Fp ]

145 °F
[solubility ]

1 M HCl: soluble0.5g/10 mL, clear, colorless
[form ]

Liquid
[pka]

10.05(at 25℃)
[color ]

Clear colorless to yellow
[Odor]

characteristic odor
[Stability:]

Stable. Incompatible with acid chlorides, acids, acid anhydrides, strong oxidizing agents, carbon dioxide.
[Water Solubility ]

soluble
[Sensitive ]

Air Sensitive & Hygroscopic
[Merck ]

14,1609
[BRN ]

1697256
[InChIKey]

VHRGRCVQAFMJIZ-UHFFFAOYSA-N
[LogP]

-0.3--0.15 at 21℃
[CAS DataBase Reference]

462-94-2(CAS DataBase Reference)
[NIST Chemistry Reference]

1,5-Diaminopentane(462-94-2)
[EPA Substance Registry System]

462-94-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R36/37:Irritating to eyes and respiratory system .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 2735 8/PG 3
[WGK Germany ]

3
[RTECS ]

SA0200000
[F ]

10
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29212900
[Hazardous Substances Data]

462-94-2(Hazardous Substances Data)
[Toxicity]

dni-mus:ast 10 mmol/L AMOKAG 33,149,79
Raw materials And Preparation ProductsBack Directory
[Raw materials]

L-Lysine-->Glutaronitrile
[Preparation Products]

5-(Diethylamino)pentylamine-->Carbamic acid, N,N'-1,5-pentanediylbis-, C,C'-bis(1,1-dimethylethyl) ester-->N'-methylpentane-1,5-diamine-->N-Boc-cadaverine-->2-N-(5-AMINOPENTYL)-AMINO-5-BROMOPYRIDINE -->1,5-Diisothiocyanatopentane-->CarbaMic acid, [5-(2,5-dihydro-2,5-dioxo-1H-pyrrol-1-yl)pentyl]-, 1,1-diMethylethyl ester
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,5-Diaminopentane(462-94-2).msds
Hazard InformationBack Directory
[Chemical Properties]

colourless to light yellow liquid with a very unpleasant smell
[Uses]

1,5-Diaminopentane is mainly used in organic synthesis.
[Definition]

ChEBI: An alkane-alpha,omega-diamine comprising a straight-chain pentane core with amino substitutents at positions 1 and 5. A colourless syrupy liquid diamine with a distinctive unpleasant odour, it is a homologue of putresceine and is formed by the bacterial decarboxylation of lysine that occurs during protein hydrolysis during putrefaction of animal tissue. It is also found in plants such as soyabean.
[Production Methods]

1,5-Diaminopentane can be prepared by methods similar to those described for 1,4-diaminobutane. The starting materials are 1,5-dichloropentane (obtainable from tetrahydropyran), glutarodinitrile, or glutaraldehyde. The compound is hygroscopic and has a very bad odor.
[General Description]

Cadaverine, a biogenic amine, belongs to the class of aliphatic diamines and is commonly found in food products including cheese, fish products, fermented sausages, fish sauces, etc. It can be used as a freshness marker and as an indicator of microbial spoilage since it is most commonly identified in food products as a result of inappropriate storage conditions and microbial contamination.
[Flammability and Explosibility]

Notclassified
[Safety Profile]

Poison by intravenous, rectal, and subcutaneous routes. Moderately toxic by skin contact. An irritant, sensitizer, and allergen. Mutagenic data. When heated to decomposition it emits highly toxic fumes of NOx.
[Purification Methods]

Purify the base by distillation, after standing over KOH pellets (at room temperature, i.e. liquid form). Its dihydrochloride has m 275o (sublimes in a vacuum), and its tetraphenyl boronate has m 164o. [Schwarzenbach et al. Helv Chim Acta 35 2333 1952, Beilstein 4 IV 1310.]
Spectrum DetailBack Directory
[Spectrum Detail]

1,5-Diaminopentane(462-94-2)MS
1,5-Diaminopentane(462-94-2)1HNMR
1,5-Diaminopentane(462-94-2)13CNMR
1,5-Diaminopentane(462-94-2)IR1
1,5-Diaminopentane(462-94-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,5-Diaminopentane, 98%(462-94-2)
[Alfa Aesar]

1,5-Diaminopentane, 98%(462-94-2)
[Sigma Aldrich]

462-94-2(sigmaaldrich)
[TCI AMERICA]

1,5-Diaminopentane,>98.0%(T)(462-94-2)
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