Identification | More | [Name]
1-Bromo-4-(trifluoromethoxy)benzene | [CAS]
407-14-7 | [Synonyms]
1-BROMO-4-(TRIFLUOROMETHOXY)BENZENE 4-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE 4-BROMO(TRIFLUOROMETHOXY)BENZENE 4-(TRIFLUOROMETHOXY)BROMOBENZENE P-BROMOTRIFLUOROMETHOXYBENZENE P-TRIFLUOROMETHOXY BROMOBENZENE TIMTEC-BB SBB006606 Benzene, 1-bromo-4-(trifluoromethoxy)- P-Bromotrifluoromethoxybenzen 4-Bromozbenzotrifluoride 1-Bromo-4-(Trifluoromethoxy)Be 4-(Trifluoromethoxy)bromobenzene 99% 4-BROMOA-TRIFLUOROMETHOXYBENZENE 4-(Trifluoromethoxy)bromobenzene99% 1-Brom-4-(trifluormethoxy)benzol 1-Bromo-4-(trifluromethoxy)benzene 4-(trifluoromethoxy)bromobenzene,1-bromo-4-(trifluoromethoxy)benzene p-Bromophenyl trifluoromethyl ether 4-Bromophenyl(trifluoromethyl) ether | [EINECS(EC#)]
206-979-2 | [Molecular Formula]
C7H4BrF3O | [MDL Number]
MFCD00040834 | [Molecular Weight]
241.01 | [MOL File]
407-14-7.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn,N,Xi | [Risk Statements ]
R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . R43:May cause sensitization by skin contact. R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37:Wear suitable protective clothing and gloves . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S37/39:Wear suitable gloves and eye/face protection . S36:Wear suitable protective clothing . | [RIDADR ]
UN 3082 9/PG 3
| [WGK Germany ]
1
| [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT | [HS Code ]
29093090 | [Toxicity]
LD50 orally in Rabbit: > 2500 mg/kg |
Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO YELLOW LIQUID | [Uses]
1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 109, p. 3708, 1987 DOI: 10.1021/ja00246a030 | [General Description]
1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene. |
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