| Identification | More | [Name]
Dichloro(1,5-cyclooctadiene)palladium(II) | [CAS]
12107-56-1 | [Synonyms]
(1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE
1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE
(CIS, CIS-1,5-CYCLOOCTADIENE)PALLADIUM(II) CHLORIDE
DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(II)
DICHLORO(1,5-CYCLOOCTYLDIENE)PALLADIUM(II)
DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADATE (II)
DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADIUM(II)
DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PALLADIUM (II)
dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladiu
dichloro[(1,2,5,6-eta)-cycloocta-1,5-diene]palladium
Dichloro(cycloocta-1,5-dienyl)palladium(II)
Dichloro(1,5-cyclooctadiene)palladium(II),99%
Dichloro-(1,5-cyclooctadiene)-palladium
DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(LL)
Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%
Dichloro(cycloocta-1,5-diene)palladium(II), Pd 37.3% | [EINECS(EC#)]
235-161-8 | [Molecular Formula]
C8H12Cl2Pd | [MDL Number]
MFCD00012412 | [Molecular Weight]
285.51 | [MOL File]
12107-56-1.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow | [Melting point ]
210 °C (dec.) (lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Soluble in dichloromethane | [form ]
crystal | [color ]
yellow | [Water Solubility ]
insoluble | [Sensitive ]
Hygroscopic | [InChI]
InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; | [InChIKey]
NEKYMUKEOUDFPP-XRGHXPOKSA-L | [SMILES]
C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6| | [CAS DataBase Reference]
12107-56-1(CAS DataBase Reference) | [EPA Substance Registry System]
12107-56-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
28439000 |
| Hazard Information | Back Directory | [Chemical Properties]
yellow | [Uses]
Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene. | [Application]
Used in alcohol protection; synthesis of carbamates, bicyclooctanes and alkene carbonylation. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | [Synthesis]
Dichloro(1,5-cyclooctadiene)palladium(II) is prepared in 96% yield by treating Palladium(II) Chloride with 1,5-cyclooctadiene in concentrated hydrochloric acid. |
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