Identification | More | [Name]
D-Camphorsulfonic acid | [CAS]
3144-16-9 | [Synonyms]
(+)-10-CAMPHORSULFONIC ACID (1S)-(+)-10-CAMPHORSULFONIC ACID (1S,4R)-2-OXO-10-BORNANESULFONIC ACID (1S)-BETA-CAMPHOR-10-SULFONIC ACID (1S)-(+)-CAMPHOR-10-SULFONIC ACID (1S)-CAMPHOR-10-SULFONIC ACID (1S)-(+)-CAMPHOR-10-SULPHONIC ACID 2-Oxobornane-10-sulphonic acid (+)-BETA-CAMPHORSULFONIC ACID (+)-CAMPHOR-10-SULFONIC ACID (+)-CAMPHOR-10-SULFONIC ACID (BETA) CSA D(+)-10-CAMPHORSULFONIC ACID D-10-CAMPHORSULFONIC ACID d-2-oxobornane-10-sulfonic acid D-(+)-CAMPHOR-10-SULFONIC ACID D-CAMPHOR-10-SULFONIC ACID D(-)-CAMPHORSULFONIC ACID D-(+)-CAMPHOR SULFONIC ACID D-CAMPHORSULFONIC ACID | [EINECS(EC#)]
221-554-1 | [Molecular Formula]
C10H16O4S | [MDL Number]
MFCD00064157 | [Molecular Weight]
232.3 | [MOL File]
3144-16-9.mol |
Chemical Properties | Back Directory | [Appearance]
white to light beige powder | [Melting point ]
196-200 °C (dec.)(lit.)
| [alpha ]
22 º (589nm, c=20, H2O 25 ºC) | [Boiling point ]
344.46°C (rough estimate) | [density ]
1.2981 (rough estimate) | [refractive index ]
21.5 ° (C=5, H2O) | [storage temp. ]
2-8°C
| [solubility ]
Exhibit moderate solubility in HCCl. | [form ]
Crystalline Powder | [pka]
1.17±0.50(Predicted) | [color ]
White to off-white | [PH]
0.3 (200g/l, H2O) | [Stability:]
Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases. | [optical activity]
[α]20/D +21.5±1°, c = 10% in H2O | [Water Solubility ]
SOLUBLE | [Sensitive ]
Hygroscopic | [Detection Methods]
T | [Merck ]
14,1734 | [BRN ]
2809675 | [InChIKey]
MIOPJNTWMNEORI-GMSGAONNSA-N | [CAS DataBase Reference]
3144-16-9(CAS DataBase Reference) | [EPA Substance Registry System]
3144-16-9(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S25:Avoid contact with eyes . S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
ED1550000
| [F ]
3-10 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29147090 |
Hazard Information | Back Directory | [Chemical Properties]
white to light beige powder | [Uses]
Used as a resolving agent, and as a catalyst for coupling dipeptides. | [Definition]
ChEBI:(S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid. | [Purification Methods]
Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer. |
|
|