Identification | More | [Name]
Chloroplatinic acid hydrate | [CAS]
26023-84-7 | [Synonyms]
Acidplatinic chloride CHLOROPLATINIC ACID CHLOROPLATINIC ACID, 6-HYDRATE CHLOROPLATINIC ACID HEXAHYDRATE CHLOROPLATINIC ACID HEXAHYDRATE(IV) DIHYDROGEN HEXACHLOROPLATINATE HEXAHYDRATE DIHYDROGEN HEXACHLOROPLATINATE(IV) HEXACHLOROPLATINIC ACID HEXACHLOROPLATINIC ACID HEXAHYDRATE HEXACHLOROPLATINIC(IV) ACID HEXAHYDRATE HEXACHLORO PLATINUM(IV) ACID HEXAHYDRATE HYDROGEN HEXACHLOROPLATINATE(+4)HEXAHYDRATE HYDROGEN HEXACHLOROPLATINATE(IV) HEXAHYDRATE PLATINIC CHLORIDE HEXAHYDRATE PLATINUM CHLORIDE PLATINUM CHLORIDE, HEXAHYDRATE PLATINUM (IV) CHLORIDE PLATINUM(IV) CHLORIDE ACID HEXAHYDRATE PLATINUM(IV) CHLORIDE HEXAHYDRATE hydrogenhexachloroplatinate(iv)hydrate,reagentacs | [EINECS(EC#)]
241-010-7 | [Molecular Formula]
Cl6H14O6Pt | [MDL Number]
MFCD00149910 | [Molecular Weight]
517.9 | [MOL File]
26023-84-7.mol |
Chemical Properties | Back Directory | [Appearance]
orange to orange-brown powder and chunks | [Melting point ]
60 °C(lit.) | [density ]
2.43 g/mL at 25 °C(lit.)
| [storage temp. ]
2-8°C
| [solubility ]
H2O: 0.5 M at 20 °C, clear, orange
| [form ]
powder and chunks
| [color ]
orange
| [Specific Gravity]
2.43 | [Water Solubility ]
Soluble in water, ethanol, ether, ethyl acetate and acetone. Insoluble in nitric acid. | [Sensitive ]
Hygroscopic | [Merck ]
14,7526 | [CAS DataBase Reference]
26023-84-7(CAS DataBase Reference) |
Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R25:Toxic if swallowed. R34:Causes burns. R42/43:May cause sensitization by inhalation and skin contact . | [Safety Statements ]
S22:Do not breathe dust . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2507 8/PG 3
| [WGK Germany ]
1
| [RTECS ]
TP1510000
| [F ]
3-8-10 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28439000 |
Hazard Information | Back Directory | [Chemical Properties]
orange to brown lumps | [Uses]
Catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink, microscopy.Dihydrogen hexachloroplatinate(IV) hexahydrate is used for the determination of potassium. It is also used for the purification of platinum by treating it with ammonium chloride followed by heating of ammonium hexachloroplatinate with hydrogen yields elemental platinum. It also finds application in catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink and microscopy. It is a precursor for the preparation of other platinum catalysts. In addition to this, it is also used as an analytical reagent. | [General Description]
Chloroplatinic acid hydrate is the most readily available compound of platinum. It may be prepared by dissolving platinum in aqua regia. Thermogravimetric analysis of this compound has been reported. The analysis shows the loss of water followed by formation of platinum tetrachloride (PtCl4) at 220 °C and β-PtCl2 at 350 °C finally decomposing to platinum metal at 500 °C. |
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