| Identification | More | [Name]
Iminostilbene | [CAS]
256-96-2 | [Synonyms]
D(-)ALPHA-FORMYLOXY-ALPHA-PHENYLACETYLCHLORIDE
D-(-)-O-FORMYL MANDELOYL CHLORIDE
FORMYLOXYMANDELOYL CHLORIDE
(-)-O-FORMYL-D-MANDELOYL CHLORIDE
R(-)-ALPHA-(FORMYLOXY)PHENYLACETYLCHLORIDE
R-FMOC
(R)-(-)-O-FORMYLMANDELOYL CHLORIDE
(R)-O-FORMYL-MANDELOYL CHLORIDE
2,3,6,7-Dibenzazepine
5-Azadibenzo(a,e)cycloheptatriene
5H-Dibenz[b,f]azepin
5H-Dibenzo(b,f)azepine
Dibenz(b,f)azepine
Stilbene, 2,2'-imino-
Iminostilben
IMINOSTILBENE (BROMINE FREE)
IMINOSTILBENE (NON-BROMINE FREE)
Iminostibene carbonyl chloride
5H-Dibenz[b,f]azepine
Iminostilbene | [EINECS(EC#)]
249-478-4 | [Molecular Formula]
C14H11N | [MDL Number]
MFCD00799229 | [Molecular Weight]
193.24 | [MOL File]
256-96-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Yellow to orange-yellow fine powder | [Melting point ]
197 °C | [Boiling point ]
221 °C(lit.)
| [density ]
1.290 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.523(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
dioxane: 50 mg/mL, clear
| [form ]
powder
| [pka]
1.71±0.20(Predicted) | [color ]
yellow to orange
| [Water Solubility ]
Soluble in ethyl acetate (25 mg/ml), water (partly), dioxane, chloroform, and DMSO. | [BRN ]
1343358 | [LogP]
4.06 | [CAS DataBase Reference]
256-96-2(CAS DataBase Reference) | [NIST Chemistry Reference]
| [EPA Substance Registry System]
5H-Dibenz[b,f]azepine (256-96-2) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi,N,Xn | [Risk Statements ]
R34:Causes burns.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [Hazard Note ]
Irritant | [HS Code ]
29339900 |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow to orange-yellow fine powder | [Uses]
Iminostilbene is mainly used as a pharmaceutical intermediate for the production of carbamazepine, Oxcarbazepine, and rhodium catalyst ligand. It is a metabolite of of carbamazepine which is used primarily in the treatment of epilepsy and neuropathic pain. | [Application]
Iminostilbene has good antioxidant effects. N-acetyl iminostilbene was synthesized by incubating iminostilbene (2.0020 g, 10.360 mmol) with acetic anhydride. | [Definition]
ChEBI: Iminostilbene is a mancude organic heterotricyclic parent that consists of a seven-membered nitrogen hetrocycle fused with two benzene rings. It has a role as a marine xenobiotic metabolite. It is a mancude organic heterotricyclic parent and a dibenzoazepine. | [Preparation]
iminostilbene synthesis: 10,11-Dihydro-5-dibenz(b,f)azepine [Iminodibenzyl, 494-19-9] as raw material was acylated by triphosgene, after bromination by bromine and dehydrobromination, reacted with sodium hydroxide in isopropanol to give Iminostilbene. | [General Description]
5H-Dibenz[b,f]azepine, a tricyclic amine with a seven-membered ring, is commonly known as iminostilbene. It is used as an intermediate or a starting material in the synthesis of many anticonvulsant drugs.It is also used as a starting material to prepare pharmacologically important dibenzoazepine-pyridazine derivatives and synthesize olefinic multidentate ligand, which is used to prepare Rh(I) complexes. | [Biochem/physiol Actions]
2-(Bromomethyl)naphthalene is a fluorescent alkyl bromide. It causes the esterification of free carboxyl groups formed at the surface of polyethylene terephthalate by enzyme hydrolysis. It acts as organic electrophile in the P4S10/acyloin reaction. |
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