| Identification | More | [Name]
2,3-O-ISOPROPYLIDENE-D-ERYTHRONOLACTONE | [CAS]
25581-41-3 | [Synonyms]
2,3-O-ISOPROPYLIDENE-D-ERYTHRONOLACTOL
(-)-2,3-O-ISOPROPYLIDENE-D-ERYTHRONO-LACTONE
2,3-O-ISOPROPYLIDENE-D-ERYTHRONOLACTONE
Furo[3,4-d]-1,3-dioxol-4(3aH)-one, dihydro-2,2-dimethyl-, (3aR,6aR)- | [Molecular Formula]
C7H10O4 | [MDL Number]
MFCD00134440 | [Molecular Weight]
158.15 | [MOL File]
25581-41-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
67-69 °C(lit.) | [Boiling point ]
259.7±35.0 °C(Predicted) | [density ]
1?+-.0.06 g/cm3(Predicted) | [refractive index ]
-117 ° (C=1, H2O) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Slightly), Water (Slightly) | [form ]
Powder | [color ]
White to Off-white | [optical activity]
[α]20/D 118°, c = 1 in H2O | [Water Solubility ]
Soluble in water | [Usage]
A chiral synthon used for the synthesis of certain natural products such as the leukotrienes | [BRN ]
1282952 | [CAS DataBase Reference]
25581-41-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [HS Code ]
2932.20.5050 |
| Hazard Information | Back Directory | [Uses]
Undergoes Aldol condensations with silyl ketene acetals. Employed in spiroannulated carbohydrate synthesis. Convergent syntheses of a hydroxylated indolizidine, carbohydrate substituted benzoquinones, and of the oxazole segment of calyculin have been accomplished using this chiral synthon. | [Uses]
As a chiral synthon, 2,3-O-Isopropylidene-D-erythronolactone can be used for the synthesis of certain natural products such as the leukotrienes.
| [Uses]
It undergoes Aldol condensations with silyl ketene acetals.1 Employed in spiroannulated carbohydrate synthesis.2 Convergent syntheses of a hydroxylated indolizidine,3 carbohydrate substituted benzoquinones,4 and of the oxazole segment of calyculin5 have been accomplished using this chiral synthon. |
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