| Identification | More | [Name]
Dibenzyl azodicarboxylate | [CAS]
2449-05-0 | [Synonyms]
AZODICARBOXYLIC ACID DIBENZYL ESTER
DBAD
DIBENZYL AZODICARBOXYLATE
diazenedicarboxylicacid,bis(phenylmethyl)ester
DIBENZYL AZODICARBOXYLATE, TECH., 90%
Azodicarboxylicaciddibenzylester~DBAD
Dibenzylazodicarboxylate,98%
Phenylmethyl N-(phenylmethoxycarbonylimino)carbamate
Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L)
Azobis(formic acid benzyl) ester
Azodiformic acid dibenzyl ester
Bis(benzyloxycarbonyl)diazene
Diazene-1,2-dicarboxylic acid dibenzyl ester
Diazenedicarboxylic acid dibenzyl ester | [EINECS(EC#)]
219-508-0 | [Molecular Formula]
C16H14N2O4 | [MDL Number]
MFCD00016737 | [Molecular Weight]
298.29 | [MOL File]
2449-05-0.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow to orange crystalline powder | [Melting point ]
43-47 °C (lit.) | [Boiling point ]
439.72°C (rough estimate) | [density ]
1.2028 (rough estimate) | [refractive index ]
1.6240 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
0-6°C | [form ]
Crystalline Powder | [color ]
Yellow to orange | [Sensitive ]
Light Sensitive | [BRN ]
2298734 | [InChI]
InChI=1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2 | [InChIKey]
IRJKSAIGIYODAN-ISLYRVAYSA-N | [SMILES]
N(C(OCC1=CC=CC=C1)=O)=NC(OCC1=CC=CC=C1)=O | [CAS DataBase Reference]
2449-05-0(CAS DataBase Reference) | [EPA Substance Registry System]
2449-05-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,F | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R11:Highly Flammable. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
3224 | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29270000 |
| Hazard Information | Back Directory | [Chemical Properties]
yellow to orange crystalline powder | [Uses]
Dibenzyl azodicarboxylate is a reagent used in the synthesis of Minocycline-d6 (M344797). Minocycline-d6 is a labeled second generation tetracycline antibiotic. Antibacterial. | [General Description]
Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides. | [Synthesis]
PIDA (phenyliodine diacetate) and DCM (dichloromethane) were added to compound dibenzyl hydrazine-1,2-dicarboxylate, and the mixture was reacted with stirring at room temperature for 30 minutes to obtain DBAD (dibenzyl azodicarboxylate) in a yield of 97%. |
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