| Identification | More | [Name]
Silver mesylate | [CAS]
2386-52-9 | [Synonyms]
METHANESULFONIC ACID, SILVER SALT
METHYLSULFONIC ACID SILVER SALT
SILVER MESYLATE
SILVER METHANESULFONATE
SMS
methanesulfonicacid,silver(1+)salt
methanesulfonicacid,silver(1++)salt
silver methanesulphonate
Sliver Methane Sulfonate solution | [EINECS(EC#)]
219-199-2 | [Molecular Formula]
CH3AgO3S | [MDL Number]
MFCD00064795 | [Molecular Weight]
202.97 | [MOL File]
2386-52-9.mol |
| Chemical Properties | Back Directory | [Appearance]
white to beige or light grey crystalline powder | [Melting point ]
252-256 °C (lit.) | [density ]
1.405 at 20℃ | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
Powder | [color ]
White to beige or light gray | [PH]
1 at 20℃ and 10g/L | [Water Solubility ]
Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane. | [Sensitive ]
Light Sensitive | [InChIKey]
MLKQJVFHEUORBO-UHFFFAOYSA-M | [Surface tension]
77.8mN/m at 1g/L and 20℃ | [Dissociation constant]
1.9 at 20℃ | [CAS DataBase Reference]
2386-52-9(CAS DataBase Reference) | [EPA Substance Registry System]
2386-52-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust . | [RIDADR ]
1759 | [WGK Germany ]
3
| [RTECS ]
PB2685000
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28432900 | [Safety Profile]
Poison by intravenous route. When heated to decomposition it emits toxic fumes of SO,. See also SULFONATES and SILVER COMPOUNDS |
| Hazard Information | Back Directory | [Chemical Properties]
white to beige or light grey crystalline powder | [Uses]
Gold Catalysts—21st Century'Gold Rush' Catalyst for: .Heterocyclization reactions . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,?-unsaturated ketones and esters | [Uses]
Silver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters. | [reaction suitability]
core: silver
reagent type: catalyst |
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