Identification | More | [Name]
3-BROMO-4-METHOXYTOLUENE | [CAS]
22002-45-5 | [Synonyms]
2-BROMO-4-METHYLANISOLE 3-BROMO-4-METHOXYTOLUENE m-Bromo-p-methoxytoluene 2-Bromo-4-methylanisole 98% 3-Bromo-4-methoxytoluene > 3-Bromo-4-methoxytoluene 98% 1-Methoxy-2-bromo-4-methylbenzene 2-Bromo-4-methyl-1-methoxybenzene 1-Bromo-2-methoxy-5-methylbenzene 2-bromo-1-methoxy-4-methyl-benzen Benzene, 2-bromo-1-methoxy-4-methyl- Methyl(2-bromo-4-methylphenyl) ether 3-BROMO-4-METHOXYTOLUENE ISO 9001:2015 REACH 3-Bromo-4-methoxytoluene, 2-Bromo-1-methoxy-4-methylbenzene | [EINECS(EC#)]
244-705-3 | [Molecular Formula]
C8H9BrO | [MDL Number]
MFCD00017783 | [Molecular Weight]
201.06 | [MOL File]
22002-45-5.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT | [HS Code ]
2909309090 |
Hazard Information | Back Directory | [Chemical Properties]
Clear colourless to light yellow liquid | [Uses]
2-Bromo-4-methylanisole may be used in the synthesis of:
- 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
- 1,8-dimethoxy-4-methylanthra-quinone
- ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide. | [Synthesis Reference(s)]
Synthetic Communications, 23, p. 779, 1993 DOI: 10.1080/00397919308009839 | [General Description]
2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate). |
|
|