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ChemicalBook--->CAS DataBase List--->2009020-38-4

2009020-38-4

2009020-38-4 Structure

2009020-38-4 Structure
IdentificationBack Directory
[Name]

Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
[CAS]

2009020-38-4
[Synonyms]

RockPhos Pd G3
Methanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II)
Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (RockPhos Pd G3)
2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium
METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3-METHOXY-6-METHYL-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ROCKPHOSPALLADACYCLEGEN.3]
[Molecular Formula]

C44H62NO4PPdS
[MDL Number]

MFCD27952542
[MOL File]

2009020-38-4.mol
[Molecular Weight]

839.434
Chemical PropertiesBack Directory
[Melting point ]

220-250 °C
[form ]

Powder
[color ]

brown
[InChIKey]

QAHMIRGGAFFMDS-UHFFFAOYSA-N
[CAS DataBase Reference]

2009020-38-4
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Questions And AnswerBack Directory
[Reaction]

  1. Palladium precatalyst used for the arylation of an aliphatic alcohol.
  2. Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions.
  3. Palladium precatalyst used for the intermolecular C-O bond formation with secondary and primary alcohols.
Reactions of 2009020-38-4
Hazard InformationBack Directory
[Uses]

Buchwald 3rd Generation Pd Precatalyst containing bulk RockPhos ligand. This system has been shown to be effective for cross-coupling reactions like the arylation of aliphatic alcohols.


Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands
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