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ChemicalBook--->CAS DataBase List--->1599466-89-3

1599466-89-3

1599466-89-3 Structure

1599466-89-3 Structure
IdentificationBack Directory
[Name]

t-BuXphos Palladacycle Gen. 4
[CAS]

1599466-89-3
[Synonyms]

Methanesulfonato(2-Di-t-butylphosphino-2,4,6-tri-i-propyl-1,1-biphenyl)(2-methylamino-1,1-biphenyl-2-yl)palladium(II)
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, [t-BuXphos Palladacycle Gen. 4]
[Molecular Formula]

C43H60NO3PPdS
[MDL Number]

MFCD28411856
[MOL File]

1599466-89-3.mol
[Molecular Weight]

893.333
Chemical PropertiesBack Directory
[form ]

Powder
[color ]

off-white to gray
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Questions And AnswerBack Directory
[Reaction]

Alternative N-methyl catalyst for mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media. Reactions of 1599466-89-3
Hazard InformationBack Directory
[Uses]

t-BuXphos Palladacycle Gen. 4 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.
[Forms and nomenclature]

Off-white to gray powder
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