| Identification | Back Directory | [Name]
Methanesulfonato(diadamantyl-n-butylphosphino)-2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 95% [cataCXium(R) A Palladacycle Gen. 3] | [CAS]
1651823-59-4 | [Synonyms]
Methanesulfonato(diadamantyl-n-butylphosphino)-2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 95% [cataCXium(R) A Palladacycle Gen. 3] | [Molecular Formula]
C37H52NO3PPdS | [MDL Number]
MFCD28144563 | [MOL File]
1651823-59-4.mol | [Molecular Weight]
728.28 |
| Chemical Properties | Back Directory | [Melting point ]
196-241 °C (decomposition) | [storage temp. ]
Keep in dark place,Inert atmosphere,2-8°C | [form ]
Powder | [color ]
off-white | [InChIKey]
VIYNMTFDXQNMCC-UHFFFAOYSA-N | [SMILES]
P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C)CCCC |
| Hazard Information | Back Directory | [Uses]
cataCXium? A Pd G3 is a Buchwald third generation precatalyst that can be used in:
- Direct ortho-arylation of pyridinecarboxylic acids.
- Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
- Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
- Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
| [reaction suitability]
reagent type: catalyst
reaction type: Cross Couplings |
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