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ChemicalBook--->CAS DataBase List--->14347-78-5

14347-78-5

14347-78-5 Structure

14347-78-5 Structure
IdentificationMore
[Name]

(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol
[CAS]

14347-78-5
[Synonyms]

2,3-ISOPROPYLIDENE-SN-GLYCEROL
2,3-O-ISOPROPYLIDENE-L-GLYCEROL
(-)-2,3-O-ISOPROPYLIDENE-SN-GLYCEROL
L-(-)-1,2-ISOPROPYLIDENEGLYCEROL
L-2,3-O-ISOPROPYLIDENE-SN-GLYCEROL
L-ALPHA,BETA-ISOPROPYLIDENEGLYCEROL
(R)-(-)-1,2-O-ISOPROPYLIDENEGLYCEROL
R-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-METHANOL
((R)-2,2-DIMETHYL-[1,3]DIOXOLAN-4-YL)-METHANOL
R-(-)-(2,2-DIMETHYL-[1,3]DIOXOLAN-4-YL)-METHANOL
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL
(R)-2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL
(R)-(-)-2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE
(R)-2,2-DIMETHYL 4-HYDROXYMETHYL-1,3-DIOXOLANE
(R)-2,3-ISOPROPYLIDENE GLYCEROL
R-(-)-2,3-O-ISOPROPYLIDENEGLYCEROL
R-GLYCEROL ACETONIDE
(R)-(-)-SOLKETAL
(R)-2,2-dimethyl-1,3-dioxalone-4-methanol
L-Glycerol-acetonide
[EINECS(EC#)]

604-360-5
[Molecular Formula]

C6H12O3
[MDL Number]

MFCD00003213
[Molecular Weight]

132.16
[MOL File]

14347-78-5.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[alpha ]

-13.7 º (neat)
[Boiling point ]

72-73 °C/8 mmHg (lit.)
[density ]

1.064 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.434
[Fp ]

176 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Liquid
[pka]

14.20±0.10(Predicted)
[color ]

Clear colorless to light yellow
[Specific Gravity]

1.062
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[optical activity]

[α]20/D 13.7°, neat
[Water Solubility ]

miscible
[Merck ]

14,5213
[BRN ]

80117
[InChIKey]

RNVYQYLELCKWAN-RXMQYKEDSA-N
[CAS DataBase Reference]

14347-78-5(CAS DataBase Reference)
[NIST Chemistry Reference]

D-Acetone glycerol(14347-78-5)
Questions And AnswerBack Directory
[Uses]

(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol is a MEK inhibitor with antitumor activity.
Safety DataBack Directory
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[RTECS ]

JI0400000
[F ]

10
[HS Code ]

29329990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Ethyl acetate-->Tetrahydrofuran-->Acetic acid-->Acetone-->Sodium borohydride-->p-Toluenesulfonic acid-->Tetrabutylammonium bromide-->Sodium periodate-->L(+)-Diethyl L-tartrate-->(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester-->1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol
[Preparation Products]

[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanamine-->(2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL)-METHYLAMINE-->2,2-DIMETHYL-4(S)-4-IODOMETHYL-1,3-DIOXALANE
Hazard InformationBack Directory
[Chemical Properties]

colourless liquid
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol(14347-78-5)1HNMR
(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol(14347-78-5)IR
(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol(14347-78-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol, 98%(14347-78-5)
[Alfa Aesar]

(R)-(-)-2,3-O-Isopropylideneglycerol, 96%(14347-78-5)
[Sigma Aldrich]

14347-78-5(sigmaaldrich)
[TCI AMERICA]

(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol,>97.0%(GC)(14347-78-5)
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