Identification | More | [Name]
GERMANIUM TETRABROMIDE | [CAS]
13450-92-5 | [Synonyms]
GERMANIUM BROMIDE GERMANIUM BROMIDE (IV) GERMANIUM (IV) BROMIDE GERMANIUM TETRABROMIDE Germane,tetrabromo- germylbromide tetrabromo-german tetrabromogermane tetrabromo-Germane tetrabromo-germaniu Germanium (IV) bromide (99.99+%-Ge) PURATREM GERMANIUM(IV) BROMIDE, 99.999% 99.999%(metalsbasis) GERMANIUM(IV) BROMIDE: (99.99%-GE) PURATREM, AMPOULED Germanium(IV) bromide, 99.999% (metals basis) Germanium(IV) tetrabromide | [EINECS(EC#)]
236-612-1 | [Molecular Formula]
Br4Ge | [MDL Number]
MFCD00016115 | [Molecular Weight]
392.26 | [MOL File]
13450-92-5.mol |
Chemical Properties | Back Directory | [Appearance]
solid | [Melting point ]
26.1 °C(lit.) | [Boiling point ]
186.5 °C(lit.) | [density ]
3.13 g/mL at 25 °C(lit.)
| [refractive index ]
1.6269 | [Fp ]
186.5°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
reacts with H2O | [form ]
Low Melting Solid/Liquid, Ampouled Under Argon | [color ]
White to gray | [Specific Gravity]
3.132 | [Stability:]
Stable. Incompatible with water, strong oxidizing agents. | [Water Solubility ]
It reacts in water. | [Sensitive ]
Moisture Sensitive | [CAS DataBase Reference]
13450-92-5(CAS DataBase Reference) | [EPA Substance Registry System]
Germane, tetrabromo- (13450-92-5) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R14:Reacts violently with water. R34:Causes burns. R37:Irritating to the respiratory system. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S27:Take off immediately all contaminated clothing . S36:Wear suitable protective clothing . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
LY5220000
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [Safety Profile]
Poison by intravenous
route. When heated to decomposition it
emits very toxic fumes of Br-. See also
GERMANIUM COMPOUNDS. |
Questions And Answer | Back Directory | [Description]
Germanium (IV) bromide is a white solid with acidic smell. It reacts violently with water. It is soluble in pure ethanol, carbon tetrachloride, benzene and ether.1 It is used as a germanium source for uses compatible with bromides and in acidic condition. It is used as a chemical gent.2
| [References]
- https://de.wikipedia.org/wiki/Germanium(IV)-bromid
- D. C. Ayres, D. G. Hellier, Dictionary of Environmentally Important Chemicals, 1998, ISBN 0-7514-0256-7
|
Hazard Information | Back Directory | [Chemical Properties]
solid ingot in glass with 99.999% purity; white crystal(s); enthalpy of vaporization 41.4 kJ/mol; can be prepared readily by reacting Ge with Br2 or with GeO2 and HBr solutions [KIR78] [STR93] [CER91] [CRC10] | [Uses]
It is used as a chemical agent, as a laboratory chemical & for manufacturing of substances. | [Purification Methods]
Purify it by simple distillation or fractionation depending on purity. It is soluble in EtOH, CHCl3, *C6H6 and Et2O. It fumes in moist air and is readily hydrolysed by water. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 718 1963]. LACHRYMATORY. |
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