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ChemicalBook--->CAS DataBase List--->116-53-0

116-53-0

116-53-0 Structure

116-53-0 Structure
IdentificationMore
[Name]

2-Methyl butyric acid
[CAS]

116-53-0
[Synonyms]

2-METHYLBUTANOIC ACID
(+/-)-2-METHYLBUTYRIC ACID
2-METHYLBUTYRIC ACID
BUTANE-2-CARBOXYLIC ACID
CARBOXYLIC ACID C5
DL-2-METHYLBUTYRIC ACID
DL-METHYLETHYLACETIC ACID
FEMA 2695
Methylbutyric acid
METHYLBUTYRIC ACID, DL-2-
METHYLETHYL ACETIC ACID
RARECHEM AL BO 0094
2-Methybutyric acid
2-methyl-butanoicaci
2-Methylbuttersαure(±)-
2-methylbutyrate
2-methylbutyric
2-methyl-butyricaci
2-Methyl-n-butyricacid
Active valeric acid
[EINECS(EC#)]

204-145-2
[Molecular Formula]

C5H10O2
[MDL Number]

MFCD00002669
[Molecular Weight]

102.13
[MOL File]

116-53-0.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to pale yellowish liquid
[Melting point ]

-70 °C
[Boiling point ]

176-177 °C (lit.)
[density ]

0.936 g/mL at 25 °C(lit.)
[vapor pressure ]

0.5 mm Hg ( 20 °C)
[FEMA ]

2695
[refractive index ]

n20/D 1.405(lit.)
[Fp ]

165 °F
[storage temp. ]

0-6°C
[solubility ]

20g/l
[form ]

Liquid
[pka]

4.8(at 25℃)
[color ]

Clear colorless to pale yellow
[Odor]

at 10.00 % in propylene glycol. pungent acid roquefort cheese
[explosive limit]

1.6-7.3%(V)
[Odor Type]

acidic
[Water Solubility ]

45 g/L (20 ºC)
[JECFA Number]

255
[BRN ]

1720486
[LogP]

1.8 at 25℃
[CAS DataBase Reference]

116-53-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Butanoic acid, 2-methyl-(116-53-0)
[EPA Substance Registry System]

116-53-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 3
[WGK Germany ]

1
[RTECS ]

EK7897000
[F ]

13
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29156090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

FUSEL OIL-->methylethylmalonic acid
[Preparation Products]

3-Methyl-butyramidine HCl-->Methylbutyric acid-->2-Methylbutyl 2-methylbutyrate-->FEMA 3632-->Butyl 2-methylbutyrate-->HEXYL ISOVALERATE STANDARD FOR GC
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Methyl butyric acid(116-53-0).msds
Questions And AnswerBack Directory
[Description]

2-methyl butyric acid has a pungent, acrid odor which is similar to Roquefort cheese with an acrid taste. At low dilutions, it has a pleasant fruity taste. It can be prepared either by decarboxylation of methyl ethyl malonic acid or by the oxidation of fermentation amyl alcohol (fusel oil). It is used as a flavor ingredient for butter, cream, cheese flavor deployment. It also provides acyl moiety for the preparation of the respective flavor esters.
[References]

[1] George A. Burdock, Encyclopedia of Food and Color Additives, Band 1, 1996
[2] T. Tachihara, H. Hashimoto, S. Ishizaki, T. Komai, A. Fujita, M. Ishikawa and T. Kitahara, Microbial resolution of 2-methylbutyric acid and its application to several chiral flavour compounds, Developments in Food Science, 2006, vol. 43, 97-100
Hazard InformationBack Directory
[Chemical Properties]

2-Methylbutyric acid has a pungent, acrid odor similar to Roquefort cheese with an acrid taste. At low dilutions, it has a pleasant, fruity taste
[Chemical Properties]

clear colorless to pale yellowish liquid
[Occurrence]

Occurring as the d-, l-, and dl-isomers; the racemic form has been reported found in angelica root oil and coffee; the d-isomer in the ester form has been identified in lavender oil. Also reported found in apple, apricot, berries, grapes, papaya, peach, guava, pineapple, potato, bell pepper, tomato, peppermint and spearmint oil, vinegar, wheat breads, cheeses, chicken, mutton, pork, hop oil, beer, cognac, rum, whiskies, cider, cocoa, coffee, tea, peanuts, passion fruit, trassi, mango, plum, tamarind, rice, corn oil, loquat, scallops, Chinese quince, maté, mammee apple and Roman chamomile oil, cranberry, grape brandy, oriental tobacco, and strawberry
[Uses]

Used in the synthesis of 2-methylbutyric anhydride
[Definition]

ChEBI: A methylbutyric acid comprising a butyric acid core carrying a 2-methyl substituent. Produced from amino acid leucine during nutrient starvation in bacteria.
[Preparation]

By decarboxylation of methyl ethyl malonic acid (with heat); also by oxidation of fermentation amyl alcohol (fusel oil).
[Aroma threshold values]

Detection: 10 to 60 ppb. Aroma characteristics at 1.0%: acidic sour, pungent, ripe fruit leather, lingonberry, dirty cheesy, fermented pineapple fruity with a woody nuance
[Taste threshold values]

Taste characteristics at 10 ppm: dirty, acidic sour, ripe fruity, with a dairy buttery and cheesy nuance
[General Description]

Enantioselective esterification of (+/-)-2-methylbutynic acid catalyzed by Chromobacterium viscosum lipase immobilized in microemulsion-based organogels has been investigated.
[Flammability and Explosibility]

Notclassified
[Biochem/physiol Actions]

Taste at 10 ppm
Spectrum DetailBack Directory
[Spectrum Detail]

2-Methyl butyric acid(116-53-0)MS
2-Methyl butyric acid(116-53-0)1HNMR
2-Methyl butyric acid(116-53-0)13CNMR
2-Methyl butyric acid(116-53-0)IR1
2-Methyl butyric acid(116-53-0)IR2
2-Methyl butyric acid(116-53-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

DL-2-Methylbutyric acid, 98%(116-53-0)
[Alfa Aesar]

2-Methylbutyric acid, 98%(116-53-0)
[Sigma Aldrich]

116-53-0(sigmaaldrich)
[TCI AMERICA]

DL-2-Methylbutyric Acid,>95.0%(GC)(T)(116-53-0)
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