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ChemicalBook--->CAS DataBase List--->1119-62-6

1119-62-6

1119-62-6 Structure

1119-62-6 Structure
IdentificationMore
[Name]

3,3'-DITHIODIPROPIONIC ACID
[CAS]

1119-62-6
[Synonyms]

2-CARBOXYETHYL DISULFIDE
3,3'-DITHIODIPROPIONIC ACID
BIS(2-CARBOXYETHYL) DISULFIDE
RARECHEM AL BO 1455
3,3’-dithiobis-propanoicaci
3,3'-dithiobispropionic acid
3,3`-Dimercaptopropionic acid
3,3-Dithiodipropionic99%
Propanoic acid, 3,3-dithiobis-
DiThio DiPropionic Acid
2-Carboxyethyl disulfide, Bis(2-carboxyethyl) disulfide
3,3'-Dithiodipropanoic acid
[EINECS(EC#)]

214-284-0
[Molecular Formula]

C6H10O4S2
[MDL Number]

MFCD00002780
[Molecular Weight]

210.27
[MOL File]

1119-62-6.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

155-158 °C(lit.)
[Boiling point ]

319.8°C (rough estimate)
[density ]

1.319 (estimate)
[refractive index ]

1.5220 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

DMSO (Sparingly), Methanol (Slightly)
[Water Solubility ]

Practically insoluble in water
[form ]

Powder
[pka]

3.94±0.10(Predicted)
[color ]

White
[BRN ]

1778543
[InChI]

InChI=1S/C6H10O4S2/c7-5(8)1-3-11-12-4-2-6(9)10/h1-4H2,(H,7,8)(H,9,10)
[InChIKey]

YCLSOMLVSHPPFV-UHFFFAOYSA-N
[SMILES]

S(CCC(O)=O)SCCC(O)=O
[CAS DataBase Reference]

1119-62-6(CAS DataBase Reference)
[EPA Substance Registry System]

Propanoic acid, 3,3'-dithiobis- (1119-62-6)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

1759
[WGK Germany ]

3
[F ]

13
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29309090
Hazard InformationBack Directory
[Chemical Properties]

white powder
[Uses]

3,3′-Dithiodipropionic acid was used as capping agent for introducing charge on gold nanoparticles surfaces.
[Uses]

Highly reactive species.
[Synthesis Reference(s)]

Tetrahedron, 41, p. 2903, 1985 DOI: 10.1016/S0040-4020(01)96614-1
Chemical and Pharmaceutical Bulletin, 34, p. 486, 1986 DOI: 10.1248/cpb.34.486
[General Description]

3,3′-Dithiodipropionic acid forms monolayers on a polycrystalline gold electrode through a self-assembly procedure to form gold 3,3′-dithiodipropionic acid self-assembled monolayer modified electrode. It is the precursor substrate in the synthesis of 3-mercaptopropionic acid-containing polythioesters. It is added as primary carbon supplement in the culture medium of novel betaproteobacterium, strain DPN7.
[Research]

Besides 3MP, also the organic sulfur compounds (OSCs) 3,3 -thiodipropionic acid (TDP) and 3,3 -dithiodipropionic acid (DTDP) are established precursor substrates for poly(3HB-co-3MP) biosynthesis in R. eutropha H16. Both precursors offer advantages in comparison to 3MP. While higher concentrations of 3MP seriously impair growth of R. eutropha H16, TDP and DTDP are nontoxic OSCs[1-2].
[References]

[1] Christina Doberstein . “Polythioester synthesis in Ralstonia eutropha H16: Novel insights into 3,3′-thiodipropionic acid and 3,3′-dithiodipropionic acid catabolism.” Journal of biotechnology 184 (2014): Pages 187-198.
[2] Jan Hendrik Wübbeler. “Dihydrolipoamide dehydrogenases of Advenella mimigardefordensis and Ralstonia eutropha catalyze cleavage of 3,3’-dithiodipropionic acid into 3-mercaptopropionic acid.” ACS Applied Electronic Materials (2010): 7023–8.
Spectrum DetailBack Directory
[Spectrum Detail]

3,3'-DITHIODIPROPIONIC ACID(1119-62-6)MS
3,3'-DITHIODIPROPIONIC ACID(1119-62-6)1HNMR
3,3'-DITHIODIPROPIONIC ACID(1119-62-6)IR1
3,3'-DITHIODIPROPIONIC ACID(1119-62-6)IR2
3,3'-DITHIODIPROPIONIC ACID(1119-62-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

[Alfa Aesar]

[Sigma Aldrich]

1119-62-6(sigmaaldrich)
[TCI AMERICA]

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