Identification | More | [Name]
N-METHYLBUTYLAMINE | [CAS]
110-68-9 | [Synonyms]
N-BUTYLMETHYLAMINE N-METHYLBUTYLAMINE N-METHYL-N-BUTYLAMINE N-N-BUTYLMETHYLAMINE 1-Butanamine,N-methyl- Butylamine, N-methyl- Butylamine,N-methyl- Butylmethylamine Methylaminobutane Methylbutylamine Methyl-N-butylamine N-Butylmethylamin N-Butyl-N-methylamine n-methyl-1-butanamin N-Methyl-1-butanamine N-Methylbutanamine N-Methylbutylamin n-methyl-butylamin N-Methyl-1-butylamine N-Methyl-1-butaneamine | [EINECS(EC#)]
203-791-2 | [Molecular Formula]
C5H13N | [MDL Number]
MFCD00009426 | [Molecular Weight]
87.16 | [MOL File]
110-68-9.mol |
Chemical Properties | Back Directory | [Appearance]
Butyl amines are highly flammable, colorless
liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer: | [Melting point ]
-75 °C | [Boiling point ]
90.5-91.5 °C(lit.) | [density ]
0.736 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.3995(lit.)
| [Fp ]
35 °F
| [storage temp. ]
Flammables area | [pka]
pK1: 10.90(+1) (25°C) | [explosive limit]
1.3%(V) | [BRN ]
1209231 | [Uses]
Intermediate. | [CAS DataBase Reference]
110-68-9(CAS DataBase Reference) | [EPA Substance Registry System]
1-Butanamine, N-methyl- (110-68-9) |
Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable. R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2945 3/PG 2
| [WGK Germany ]
3
| [RTECS ]
EO5250000
| [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29211999 | [Safety Profile]
Poison by intravenous
route. Moderately toxic by ingestion, skin
contact, and intraperitoneal routes. Mildly
toxic by inhalation. A skin and severe eye
irritant. Flammable liquid when exposed to
heat, sparks, or flame. To fight fire, use
alcohol foam. When heated to
decomposition it emits toxic fumes of NOx.
See also AMINES. | [Hazardous Substances Data]
110-68-9(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: 420 mg/kg LD50 dermal Rabbit 932 mg/kg |
Hazard Information | Back Directory | [General Description]
A water-white liquid with an ammonia-like odor. Density 0.736 g/cm3 and flash point 35°F (Aldrich) .Vapors heavier than air. Used to make other chemicals. | [Reactivity Profile]
N-METHYLBUTYLAMINE(110-68-9) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
Highly flammable. Slightly soluble in water. | [Hazard]
Flammable, dangerous fire risk. | [Health Hazard]
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Potential Exposure]
Alert: (n-isomer): Possible risk of
forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic
reaction), (sec-isomer): Drug. n-Butylamine is used in
pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying
agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a
fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate
(a lube oil additive); as an intermediate in the production
of rubber and in rust preventatives and emulsion deterrents
in petroleum products. It is used in the manufacture of
several drugs | [Fire Hazard]
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Rinse out mouth and do not induce vomiting.
Medical observation is recommended for 24 to 48 hours
after breathing overexposure, as pulmonary edema may be
delayed. As first aid for pulmonary edema, a doctor or
authorized paramedic may consider administering a drug or
other inhalation therapy | [Shipping]
UN1125 n-Butylamine, Hazard Class: 3; Labels:
3—Flammable liquid, 8—Corrosive material. UN2014
Isobutylamine, Hazard Class: 3; Labels: 3—Flammable
liquid, 8—Corrosive material | [Incompatibilities]
May form explosive mixture with air.
May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts
with strong oxidizers and acids, causing fire and explosion
hazard. Incompatible with organic anhydrides; isocyanates,
vinyl acetate; acrylates, substituted allyls; alkylene oxides;
epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in
presence of moisture. The tert-isomer will attack some
forms of plastics | [Chemical Properties]
Butyl amines are highly flammable, colorless
liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer: | [Chemical Properties]
CLEAR COLOURLESS LIQUID | [Waste Disposal]
Use a licensed professional
waste disposal service to dispose of this material. Dissolve
or mix the material with a combustible solvent and burn in
a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed. | [Definition]
ChEBI: A secondary aliphatic amine having methyl and n-butyl as the two alkyl groups. |
|
Company Name: |
Alfa Aesar
|
Tel: |
400-6106006 |
Website: |
http://chemicals.thermofisher.cn |
Company Name: |
Energy Chemical
|
Tel: |
021-021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
|