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ChemicalBook--->CAS DataBase List--->110-06-5

110-06-5

110-06-5 Structure

110-06-5 Structure
IdentificationMore
[Name]

DI-TERT-BUTYL DISULFIDE
[CAS]

110-06-5
[Synonyms]

2,2,5,5-TETRAMETHYL-3,4-DITHIAHEXANE
2,2'-DITHIOBIS(2-METHYLPROPANE)
DI-T-BUTYL DISULFIDE
DI-TERT-BUTYL DISULDIDE
DI-TERT-BUTYL DISULFIDE
TERT-BUTYL DISULFIDE
(tert-C4H9S)2
2-(tert-Butyldisulfanyl)-2-methylpropane
Bis(1,1-dimethylethyl) disulfide
Bis(1,1-dimethylethyl) disulphide
Disulfide, bis(1,1-dimethylethyl)
disulfide,bis(1,1-dimethylethyl)
Di-tert-butyl disulphide
t-Butyldisulfide
terc-Butyldisulfide
Bis(1,1-dimethylethyl) persulfide
Di-tert-butyl perdisulfide
Di-tert-butyl persulfide
Ditert-butyl persulfide
[EINECS(EC#)]

203-734-1
[Molecular Formula]

C8H18S2
[MDL Number]

MFCD00008838
[Molecular Weight]

178.36
[MOL File]

110-06-5.mol
Chemical PropertiesBack Directory
[Appearance]

clear pale yellow to yellow liquid
[Melting point ]

-5 °C
[Boiling point ]

200-201 °C(lit.)
[density ]

0.923 g/mL at 25 °C(lit.)
[vapor density ]

5 (vs air)
[vapor pressure ]

51.7 mm Hg ( 37.7 °C)
[refractive index ]

n20/D 1.490(lit.)
[Fp ]

144 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

Chloroform (Sparingly), Ethanol (Slightly)
[form ]

Liquid
[color ]

Clear pale yellow to yellow
[explosive limit]

0.8%(V)
[Odor Threshold]

0.0018ppm
[BRN ]

1698170
[InChIKey]

BKCNDTDWDGQHSD-UHFFFAOYSA-N
[LogP]

4.698 (est)
[CAS DataBase Reference]

110-06-5(CAS DataBase Reference)
[EPA Substance Registry System]

Disulfide, bis(1,1-dimethylethyl) (110-06-5)
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

2
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29309090
[Toxicity]

LD50 orally in Rabbit: 6200 mg/kg LD50 dermal Rabbit > 2000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

T-BUTYL TRIFLUOROACETATE-->TERT-BUTYL SULFIDE
[Preparation Products]

(R)-(+)-2-Methyl-2-propanesulfinamide-->2-Propanesulfinic acid,2-methyl--->(S)-tert-Butanethiosulfinate-->(R)-tert-Butanethiosulfinate-->Stannane, [(1,1-dimethylethyl)thio]trimethyl-
Hazard InformationBack Directory
[Chemical Properties]

clear pale yellow to yellow liquid
[Uses]

Di-tert-Butyl Disulfide is a general reagent used in the synthesis of a novel neuropeptide Y (NPY) Y5 receptor antagonist Velneperit) used in the treatment of obesity.
[Uses]

Di-tert-butyl disulfide is used in the preparation of gold-supported thin film from symmetrical and mixed disulphide adsorbates.
Mechanism of the oxidation of di-tert-butyl disulfide in the presence of H2O2 catalyzed by bis(acetylacetonato)oxovanadium and a chiral Schiff-base ligand has been investigated.
Di-tert-butyl disulfide has been used in the preparation of gold-supported thin film from symmetrical and mixed disulphide adsorbates.
[Synthesis Reference(s)]

Synthetic Communications, 13, p. 611, 1983 DOI: 10.1080/00397918308059536
Synthesis, p. 669, 1978 DOI: 10.1055/s-1978-24844
Tetrahedron Letters, 31, p. 3591, 1990 DOI: 10.1016/S0040-4039(00)94450-2
[General Description]

Mechanism of the oxidation of di-tert-butyl disulfide in the presence of H2O2 catalyzed by bis(acetylacetonato)oxovanadium and a chiral Schiff-base ligand has been investigated.
Questions And AnswerBack Directory
[Description]

Di-tert-butyl disulfide is one of the important organic intermediates.It is an important raw material for the synthesis of disulfide bond-containing sulfinyl and oxythio compounds. It can be used as a vulcanizing agent for rubber and elastomers in industry. It is also a monomer for the synthesis of proteins and other biologically active molecules.

Spectrum DetailBack Directory
[Spectrum Detail]

Di-tert-butyl disulfide(110-06-5)MS
Di-tert-butyl disulfide(110-06-5)1HNMR
Di-tert-butyl disulfide(110-06-5)13CNMR
Di-tert-butyl disulfide(110-06-5)IR1
Di-tert-butyl disulfide(110-06-5)IR2
Di-tert-butyl disulfide(110-06-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

tert-Butyl disulfide, 98%(110-06-5)
[Sigma Aldrich]

110-06-5(sigmaaldrich)
[TCI AMERICA]

Di-tert-butyl Disulfide,>97.0%(GC)(110-06-5)
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