Identification | More | [Name]
Dibutyl phosphate | [CAS]
107-66-4 | [Synonyms]
BUTYL PHOSPHATE DIBUTYL ACID O-PHOSPHATE DIBUTYL HYDROGEN PHOSPHATE DIBUTYL PHOSPHATE DIBUTYL PHOSPHONATE DI(BUTYL) PHOSPHORIC ACID DI-N-BUTYL PHOSPHATE MONOBUTYL PHOSPHATE PHOSPHORIC ACID BUTYL ESTER PHOSPHORIC ACID DIBUTYL ESTER PHOSPHORIC ACID DI-N-BUTYL ESTER dibutylacidphosphate di-n-butylhydrogenphosphate dp4(couplingagent) hdbp phosphatededibutyle di-n-butylphosphoric acid Phosphorsuredi-n-butylester DIBUTYL PHOSPHATE (DBP) Di-n-butyl phosphate, 97+% | [EINECS(EC#)]
203-509-8 | [Molecular Formula]
C8H19O4P | [MDL Number]
MFCD00015245 | [Molecular Weight]
210.21 | [MOL File]
107-66-4.mol |
Chemical Properties | Back Directory | [Appearance]
Dibutyl phosphate is a pale amber to
brown, odorless liquid. | [Melting point ]
-13 °C | [Boiling point ]
250 °C | [density ]
1.06 g/mL at 20 °C(lit.)
| [vapor pressure ]
0Pa at 20℃ | [refractive index ]
n20/D 1.428
| [Fp ]
188 °C
| [storage temp. ]
Store below +30°C. | [solubility ]
Chloroform (Soluble), Methanol (Slightly) | [form ]
Liquid | [pka]
1.53±0.50(Predicted) | [color ]
Clear | [Specific Gravity]
1.1 | [Water Solubility ]
insoluble | [BRN ]
607224 | [Exposure limits]
ACGIH: TWA 5 mg/m3 (Skin) OSHA: TWA 1 ppm(5 mg/m3) NIOSH: IDLH 30 ppm; TWA 1 ppm(5 mg/m3); STEL 2 ppm(10 mg/m3) | [InChIKey]
JYFHYPJRHGVZDY-UHFFFAOYSA-N | [LogP]
-0.9 at 25℃ | [CAS DataBase Reference]
107-66-4(CAS DataBase Reference) | [EPA Substance Registry System]
107-66-4(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
R37/38:Irritating to respiratory system and skin . R41:Risk of serious damage to eyes. R38:Irritating to the skin. R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S39:Wear eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S25:Avoid contact with eyes . | [RIDADR ]
3261 | [WGK Germany ]
1
| [RTECS ]
TB9605000
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29199000 | [Safety Profile]
Moderately toxic by
ingestion. When heated to decomposition it
emits toxic fumes of POx. See also
PHOSPHATES. | [Hazardous Substances Data]
107-66-4(Hazardous Substances Data) | [IDLA]
30 ppm |
Hazard Information | Back Directory | [General Description]
Pale-amber odorless liquid. Mp:-13°C, bp: 135-138°C. Density: 1.06 g cm-3. Moderately soluble in water (18 g/L at 20°C). | [Reactivity Profile]
DIBUTYL PHOSPHATE Is non-flammable, but combustible (flash point 188°C). Auto-ignition temperature is 420°C. Emits irritating or toxic fumes in a fire. Is a moderately strong acid obtained by the partial esterification of phosphoric acid. Reacts exothermically and vigorously with bases. Incompatible with strong oxidizing agents, alkali metals, heat, or plastic. Reacts with many metals liberating flammable/explosive hydrogen gas. | [Potential Exposure]
This material is used as a catalyst in
organic synthesis. | [First aid]
Move victim to fresh air. Call 911 or emergency
medical service. Give artificial respiration if victim is not
breathing. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respira-
tion with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device.
Administer oxygen if breathing is difficult. Remove and
isolate contaminated clothing and shoes. In case of contact
with substance, immediately flush skin or eyes with run-
ning water for at least 20 minutes. For minor skin contact,
avoid spreading material on unaffected skin. Keep victim
warm and quiet. Effects of exposure (inhalation, ingestion,
or skin contact) to substance may be delayed. Ensure that
medical personnel are aware of the material(s) involved
and take precautions to protect themselves. Medical obser-
vation is recommended for 24 to 48 hours after breathing
overexposure, as pulmonary edema may be delayed.
As first aid for pulmonary edema, a doctor or authorized
paramedic may consider administering a drug or other
inhalation therapy. | [Shipping]
UN1760 Corrosive liquids, n.o.s., Hazard class: 8;
Labels: 8-Corrosive material, Technical Name Required.
UN3261 Corrosive solid, acidic, organic, n.o.s., Hazard
class: 8; Labels: 8-Corrosive material, Technical Name
Required. | [Incompatibilities]
Dibutyl phosphate is a medium strong
acid. Incompatible with oxidizers (chlorates, nitrates, per-
oxides, permanganates, perchlorates, chlorine, bromine,
fluorine, etc.); contact may cause fires or explosions. Keep
away from alkaline materials, strong bases, strong acids,
oxoacids, and epoxides. Attacks many metals forming flammable and explosive hydrogen gas. Attacks some plas-
tics, rubber, and coatings. | [Description]
Dibutyl phosphate is a pale amber to brown,odorless liquid. Molecular weight = 210.24; Specificgravity (H2O:1) = 1.06; Boiling point = (decomposes)135-138℃; Freezing/Melting point = 213℃; Vapor pressure-1 mmHg at 20℃; Flash point = 188℃ (oc);Autoignition temperature = 420℃. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 2, Reactivity 0. Practically insoluble in water. | [Chemical Properties]
clear liquid | [Chemical Properties]
Dibutyl phosphate is a pale amber to
brown, odorless liquid. | [Uses]
Dibutyl phosphate is used as a plasticizer for polymer system and hydraulic fluid directly and used as a catalyst for cross-linking in paint industry. It is used as an antifoam agent in ore separation process and as an antistatic agent in the textile industry. It can be used as a precursor for antistatics, as a mould release agent in polyurethane applications and, as a non volatile acidic catalyst soluble in organic media. | [Uses]
Pale amber liquid | [Definition]
ChEBI: Dibutyl phosphate is a dialkyl phosphate. | [Health Hazard]
Dibutyl phosphate is an irritant
of the eyes and mucous membranes. | [Flammability and Explosibility]
Nonflammable | [storage]
Color Code—White: Corrosive or Contact Hazard;Store separately in a corrosion-resistant location. Prior toworking with this chemical you should be trained on its properhandling and storage. Dibutyl phosphate must be stored toavoid contact with strong oxidizers, such as chlorine, chlorinedioxide, and bromine, since violent reactions occur. |
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