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ChemicalBook--->CAS DataBase List--->1031-93-2

1031-93-2

1031-93-2 Structure

1031-93-2 Structure
IdentificationMore
[Name]

DIPHENYL(P-TOLYL)PHOSPHINE
[CAS]

1031-93-2
[Synonyms]

(4-METHYLPHENYL)(DIPHENYL)PHOSPHINE
DIPHENYL-4-METHYLPHENYLPHOSPHINE
DIPHENYL-4-TOLYLPHOSPHINE
DIPHENYL(P-TOLYL)PHOSPHINE
P-TOLYLDIPHENYLPHOSPHINE
Phosphine, (4-methylphenyl)diphenyl-
p-Tolyldiphenylphosphine,min.96%
p-Tolyldiphenylphosphine, 96+%
p-Tolyldiphenylphosphine, min. 96%
4-(Diphenylphosphino)toluene
p-Methylphenyldiphenylphosphine
[EINECS(EC#)]

213-848-3
[Molecular Formula]

C19H17P
[MDL Number]

MFCD00008543
[Molecular Weight]

276.31
[MOL File]

1031-93-2.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

66-68 °C (lit.)
[Boiling point ]

250 °C(Press: 14 Torr)
[storage temp. ]

Sealed in dry,2-8°C
[form ]

crystal
[color ]

white
[BRN ]

646709
[CAS DataBase Reference]

1031-93-2(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R38:Irritating to the skin.
R37:Irritating to the respiratory system.
R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S39:Wear eye/face protection .
S37:Wear suitable gloves .
[WGK Germany ]

3
[PackingGroup ]

III
[HS Code ]

29319090
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

Reactant for:
  • Three-component cyclization
  • Probing coordination ability via a palladium pincer complex
  • Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:
  • Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
  • Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
  • InP nanofibers / metal phosphide nanostructures
  • Peroxyl radical cations via pulse radiolysis one-electron oxidations
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 52, p. 748, 1987 DOI: 10.1021/jo00381a008
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Spectrum DetailBack Directory
[Spectrum Detail]

DIPHENYL(P-TOLYL)PHOSPHINE(1031-93-2)1HNMR
DIPHENYL(P-TOLYL)PHOSPHINE(1031-93-2)IR
DIPHENYL(P-TOLYL)PHOSPHINE(1031-93-2)FT-IR
DIPHENYL(P-TOLYL)PHOSPHINE(1031-93-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Diphenyl(p-tolyl)phosphine, 96%(1031-93-2)
[Alfa Aesar]

Diphenyl(p-tolyl)phosphine, 96%(1031-93-2)
[Sigma Aldrich]

1031-93-2(sigmaaldrich)
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