| Identification | More | [Name]
3-Picoline-N-oxide | [CAS]
1003-73-2 | [Synonyms]
3-METHYLPYRIDINE 1-OXIDE
3-METHYLPYRIDINE N-OXIDE
3-PICOLINE-N-OXIDE
BETA-PICOLINE-N-OXIDE
3-methyl-pyridin1-oxide
3-Picoline, 1-oxide
3-picoline-oxide
beta-Picoline 1-oxide
N-oxideof3-methylpyridine
Pyridine,3-methyl-,1-oxide
3-Methylpyrine-N-Oxide
3-Methylpyridin-N-oxid
B-Picoline-N-oxide
3-PICOLINE-N-OXIDE 95+%
BETA PICOLINE OXIDE, 97%
Beta-picoline N-oxide, 3-Picoline N-oxide
β-Picoline 1-oxide | [EINECS(EC#)]
213-714-4 | [Molecular Formula]
C6H7NO | [MDL Number]
MFCD00006203 | [Molecular Weight]
109.13 | [MOL File]
1003-73-2.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing . | [WGK Germany ]
1
| [RTECS ]
UT5799000
| [F ]
3-10 | [TSCA ]
Yes | [HS Code ]
29333990 | [Toxicity]
mouse,LD50,intraperitoneal,1689mg/kg (1689mg/kg),Toxicon. Vol. 23, Pg. 815, 1985. |
| Hazard Information | Back Directory | [Chemical Properties]
PALE YELLOW TO BROWN CRYSTALLINE LOW MELTING MASS | [Uses]
An intermediate in the preparation of nicotine derivatives. | [Purification Methods]
Purify the N-oxide by careful fractionation in vacuo. The distillate remains supercooled for several days before solidifying. It is a slightly hygroscopic solid which could melt in the hand. The picrate has m 149-151o (from EtOH). [Taylor & Corvetti Org Synth Coll Vol IV 654 1963, IR: Katritzky et al. J Chem Soc 3680 1959, Jaffé & Doak J Am Chem Soc 77 4441, 4481 1955, Boekelheide & Linn J Am Chem Soc 76 1286 1954]. [Beilstein 20 III/IV 2719, 20/5 V 517.] |
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