PENTYL ETHER synthesis
- Product Name:PENTYL ETHER
- CAS Number:693-65-2
- Molecular formula:C10H22O
- Molecular Weight:158.28
2、It can be prepared from iso-Amylbromide and Sodium amylalcoholate.
110-62-3
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$13.44/25ML
693-65-2
75 suppliers
$54.00/25mL
Yield: 96%
Reaction Conditions:
with 1,1,3,3-Tetramethyldisiloxane;copper(II) bis(trifluoromethanesulfonate) in dichloromethane at 20; for 1 h;
Steps:
4.5. General procedure for reductive etherification of aldehydes and ketones
General procedure: In a screw-capped vial, 3.7 mg Cu(OTf)2 (0.01 mmol, 1 mol %) and 0.1 mL TMDS (80.6 mg, 0.6 mmol, 1.2 Si-H mol/mol substrate) were introduced to a solution of aldehyde or ketone (1 mmol) in 1.5 mL CH2Cl2. After stirring for 1 h at room temperature, the reaction was quenched with 4 mL H2O. The organic layer was extracted with CH2Cl2, dried with anhydrous MgSO4, and evaporated under reduced pressure. The crude was purified by silica gel column chromatography to obtain the symmetrical ether.
References:
Zhang, Yin-Jie;Dayoub, Wissam;Chen, Guo-Rong;Lemaire, Marc [Tetrahedron,2012,vol. 68,# 36,p. 7400 - 7407] Location in patent:experimental part
71-41-0
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$9.33/100 mL
693-65-2
75 suppliers
$54.00/25mL
71-41-0
439 suppliers
$9.33/100 mL
543-59-9
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$20.00/25ml
693-65-2
75 suppliers
$54.00/25mL
71-41-0
439 suppliers
$9.33/100 mL
100-51-6
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$5.00/100g
693-65-2
75 suppliers
$54.00/25mL
103-50-4
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6382-14-5
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