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ChemicalBook CAS DataBase List N-CHLOROACETYL-2,6-DIETHYLANILINE
6967-29-9

N-CHLOROACETYL-2,6-DIETHYLANILINE synthesis

3synthesis methods
-

Yield:6967-29-9 82.72%

Reaction Conditions:

with triethylamine in dichloromethane at 0 - 20; for 6 h;

Steps:

1 General procedure for the synthesis of 12a-g
General procedure: 2-chloroacetyl chloride (1.5 mmol) was added dropwise to a mixture of amine (1 mmol) and triethylamine (3 mmol) in 20 mL dichloromethane originally at 0 °C with stirring. Then the resulting mixture was cooled to ambient temperature and stirred for 6 h. After removal of dichloromethane solvents on a rotary evaporator, water was added and extract with ethyl acetate (3 × 30 mL). The organic layer was combined and dried with sodium sulfate. The solution was evaporated to give the crude product, which was purified by Silica gel column chromatography with ethyl acetate-petroleum ether as eluent.

References:

Zhang, Mingming;Zhu, Weiliang;Li, Yingxia [European Journal of Medicinal Chemistry,2013,vol. 62,p. 301 - 310]

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