DL-Phenylalanine synthesis
- Product Name:DL-Phenylalanine
- CAS Number:150-30-1
- Molecular formula:C9H11NO2
- Molecular Weight:165.19
156-06-9
181 suppliers
$45.00/1g
150-30-1
553 suppliers
$10.00/25G
Yield:150-30-1 62%
Reaction Conditions:
with [Cp*Ir(N-phenyl-2-pyridinecarboxamidate)Cl];ammsnium formate in methanol at 37; for 6 h;chemoselective reaction;
Steps:
General Procedure for Reductive Amination of α-Ketoacids
General procedure: α-Ketoacid (0.2 mmol) and Ir1 (1 mol%) were added to a 1.5-dram vial equipped with amagnetic stir bar in methanol (1 mL). Solid HCOONH4 (2 mmol, 10 equiv.) was added to thevial and the solution was stirred at 37 °C for 6 h. The precipitate was filtered, washed with asmall amount of cold methanol, and dried under vacuum to give the desired α-amino acid.
References:
Nguyen, Dat P.;Sladek, Rudolph N.;Do, Loi H. [Tetrahedron Letters,2020,vol. 61,# 32,art. no. 152196] Location in patent:supporting information
828-01-3
152 suppliers
$21.00/1g
150-30-1
553 suppliers
$10.00/25G
![Benzenepropanamide, α-[(2-phenylacetyl)amino]-](/CAS/20210305/GIF/83556-31-4.gif)
81477-94-3
264 suppliers
$6.00/1g
100-39-0
434 suppliers
$10.00/10g
150-30-1
553 suppliers
$10.00/25G
3235-26-5
2 suppliers
$28.60/50mg
150-30-1
553 suppliers
$10.00/25G