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ChemicalBook CAS DataBase List Bis[4-(4-aminophenoxy)phenyl]sulfone
13080-89-2

Bis[4-(4-aminophenoxy)phenyl]sulfone synthesis

5synthesis methods
-

Yield:-

Reaction Conditions:

in 1-methyl-pyrrolidin-2-one;water

Steps:

1 EXAMPLE 1
At this temperature, a solution of 140.9 g (0.49 mol) of 4,4'-dichlorodiphenyl sulfone in 100 ml of N-methylpyrrolidone is added. The internal temperature is then continuously increased to 170° C. In the meantime, the toluene used is distilled off at an internal temperature of about 110° C. The temperature is maintained at 170° C. for 5 hours and then lowered to 70° C. At this temperature, 1.5 l of a water/methanol mixture (1:1) is slowly added, as a result of which the 4,4'-bis(4-aminophenoxy)diphenyl sulfone formed precipitates. The mixture is cooled to room temperature. The precipitated product is filtered off, washed with water and dried.

References:

Huels Aktiengesellschaft US5118848, 1992, A

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