(5-METHYL-2-FURYL)METHANOL synthesis

15synthesis methods

Product Name:(5-METHYL-2-FURYL)METHANOL
CAS Number:3857-25-8
Molecular formula:C6H8O2
Molecular Weight:112.13

67-47-0 Synthesis

67-47-0
587 suppliers
$5.00/100mg

98-00-0
468 suppliers
$23.00/25mL

625-86-5 Synthesis

625-86-5
198 suppliers
$20.00/25mL

3857-25-8
108 suppliers
$45.00/500 mg

Yield:98-00-0 62% ，625-86-5 15% ，3857-25-8 5%

Reaction Conditions:

with isopropyl alcohol in decane at 160; under 15001.5 Torr; for 8 h;Autoclave;Inert atmosphere;

Steps:

3; 5 Example 3: Hydrogenolysis of HMF or Furfural:
General procedure: Example 3: Hydrogenolysis of HMF or Furfural: All the reactions were carried out using 100 mL Parr autoclave (SS316). In a typical experiment, the reactor was charged with 1 mmol HMF (or 5 mmol furfural), hydrogen donor (25 mL), n-decane (0.2 g, internal standard) and required amount of freshly prepared catalyst. The reactor contents were mixed thoroughly and the reactor was sealed, purged 2-3 times with N₂ and pressurized to 20 bar N₂ pressure. Subsequently, the reaction vessel was heated under stirring at required temperature for a desired duration. Liquid samples were withdrawn periodically during the reaction and analyzed by GC (Agilent 7890A) equipped with a flame ionization detector (FID) having CP Sil 8CB capillary column (30 m length, 0.25 mm diameter). Product identification was done using authentic standards and GC-MS (Varian, Saturn 2200) analysis.

References:

COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH;CHILUKURI, Satyanarayana Veera Venkata;NAGPURE, Atul Sopan WO2017/42838, 2017, A1 Location in patent:Page/Page column 17; 21-28

67-47-0 Synthesis

67-47-0
587 suppliers
$5.00/100mg

3857-25-8
108 suppliers
$45.00/500 mg

References