4'-FORMYL-BIPHENYL-4-CARBOXYLIC ACID ETHYL ESTER synthesis
- Product Name:4'-FORMYL-BIPHENYL-4-CARBOXYLIC ACID ETHYL ESTER
- CAS Number:70917-02-1
- Molecular formula:C16H14O3
- Molecular Weight:254.28
Yield:70917-02-1 366 mg
Reaction Conditions:
Stage #1: 4-iodobenzoic acid ethyl esterwith indium(III) chloride;chloro-trimethyl-silane;lithium chloride;zinc in tetrahydrofuran at 50; for 2 h;Inert atmosphere;Schlenk technique;Sealed tube;
Stage #2: 4-bromo-benzaldehydewith 2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl;palladium diacetate in tetrahydrofuran at 20; for 1 h;Inert atmosphere;Schlenk technique;Sealed tube;Negishi Coupling;
References:
Benischke, Andreas D.;Le Corre, Grégoire;Knochel, Paul [Chemistry - A European Journal,2017,vol. 23,# 4,p. 778 - 782] Location in patent:supporting information
![[4-(Ethoxycarbonyl)phenyl]tributylstannane](/CAS/GIF/294210-67-6.gif)
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