ChemicalBook CAS DataBase List 4,4'-Bis(N-carbazolyl)-1,1'-biphenyl

4,4'-Bis(N-carbazolyl)-1,1'-biphenyl synthesis

14synthesis methods

Product Name:4,4'-Bis(N-carbazolyl)-1,1'-biphenyl
CAS Number:58328-31-7
Molecular formula:C36H24N2
Molecular Weight:484.59

92-86-4 Synthesis

92-86-4
387 suppliers
$15.00/25g

86-74-8 Synthesis

86-74-8
334 suppliers
$10.00/5g

342638-54-4 Synthesis

342638-54-4
125 suppliers
$45.00/2.5mg

9H-Carbazole, 9,9'-[1,1'-biphenyl]-3,4'-diylbis-

1325751-60-7
2 suppliers
inquiry

58328-31-7
232 suppliers
$22.00/1g

Yield:58328-31-7 77% ，342638-54-4 8.5% ，1325751-60-7 4%

Reaction Conditions:

with potassium tert-butylate in toluene at 130 - 140; for 48 h;Inert atmosphere;Autoclave;regioselective reaction;

Steps:

Synthesis of bis (9H-carbozol-9-yl)-biphenyls 2 (general procedure).
General procedure: Potassium tertbutoxide (1.12 g, 10 mmol) and carbazole (1.67 g, 10 mmol) were added to appropriate dihalobiphenyl 1 (1 mmol) in dry toluene (20 mL). The mixture was heated in a glass autoclave under argon at 130-140 C for 48 h.The resulting suspension was diluted with water to remove inorganic impurities. The organic layer was separated, concentrated to dryness, and chromatographed on silica gel using a 0-10% acetone solution in hexane.

References:

Kovalev;Pavlyuk;Zaripov;Zyryanov;Kopchuk;Rusinov;Chupakhin [Russian Chemical Bulletin,2015,vol. 64,# 8,p. 1978 - 1981][Izv. Akad. Nauk, Ser. Khim.,2015,# 8,p. 1978 - 1981,4]

FullText

3001-15-8 Synthesis