3'-METHYL [1,1'-BIPHENYL]-2-CARBOXALDEHYDE synthesis
- Product Name:3'-METHYL [1,1'-BIPHENYL]-2-CARBOXALDEHYDE
- CAS Number:216443-17-3
- Molecular formula:C14H12O
- Molecular Weight:196.24
![2-Propanamine, N-[(2-methoxyphenyl)methylene]-2-methyl-](/CAS/20210305/GIF/82632-38-0.gif)
82632-38-0
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28987-79-3
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216443-17-3
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Yield:216443-17-3 92%
Reaction Conditions:
Stage #1: N-tert-butyl-1-(2-methoxyphenyl)methaniminewith chromium dichloride in tetrahydrofuran at 25; for 0.0833333 h;Schlenk technique;Inert atmosphere;
Stage #2: m-tolylmagnesium bromide in tetrahydrofuran at 25; for 5 h;Schlenk technique;Inert atmosphere;
Stage #3: with hydrogenchloride in tetrahydrofuran;water at 25; for 3 h;Schlenk technique;Inert atmosphere;
References:
Cong, Xuefeng;Tang, Huarong;Zeng, Xiaoming [Journal of the American Chemical Society,2015,vol. 137,# 45,p. 14367 - 14372] Location in patent:supporting information
615-37-2
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18982-54-2
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216443-17-3
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17933-03-8
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6630-33-7
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216443-17-3
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591-17-3
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82632-38-0
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216443-17-3
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$45.00/50mg
17933-03-8
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89-98-5
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216443-17-3
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$45.00/50mg