ChemicalBook CAS DataBase List 3,6-Diphenyl-9H-carbazole

3,6-Diphenyl-9H-carbazole synthesis

11synthesis methods

Product Name:3,6-Diphenyl-9H-carbazole
CAS Number:56525-79-2
Molecular formula:C24H17N
Molecular Weight:319.4

6825-20-3 Synthesis

6825-20-3
329 suppliers
$5.00/5g

143-66-8 Synthesis

143-66-8
446 suppliers
$7.00/5g

56525-79-2
190 suppliers
$16.00/1g

Yield:56525-79-2 89%

Reaction Conditions:

with tetrabutylammomium bromide;sodium carbonate;palladium dichloride in acetone; for 36 h;Reflux;Inert atmosphere;

Steps:

1.I; 5.I; 9.I (I) Synthesis of 3,6-diphenyl-9H-carbazole, the reaction formula is as follows

Add 3,6-dibromo-9H-carbazole (2.6g, 8mmol), NaBPh4 (2.736g, 8mmol), tetrabutylammonium bromide (TBAB) (0.12g, 0.5mmol), chlorinated into a 250mL three-necked flask Palladium (0.05g, 0.25mmol), 30ml of 2M sodium carbonate solution, 120ml of acetone, reflux for 36h under nitrogen.The acetone was evaporated, and the aqueous layer was extracted with dichloromethane. The extract was washed with water and dried over anhydrous magnesium sulfate. The white flocculent product 3,6-diphenyl-9H-carbazole (2.3g, yields: 89%), the eluent is petroleum ether: dichloromethane = 2:1.Melting point: 177.1°C.

References:

CN107602443,2020,B Location in patent:Paragraph 0030-0040; 0133; 0134; 0201; 0202

6825-20-3 Synthesis

6825-20-3
329 suppliers
$5.00/5g

98-80-6 Synthesis